32201-M

Acetone

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.5% (GC)

• Linear Formula: CH₃COCH₃
• CAS Number: 67-64-1
• Molecular Weight: 58.08
• NACRES: NA.02
• PubChem Substance ID: 329754097
• eCl@ss: 39021201
• UNSPSC Code: 12352115
• EC Number: 200-662-2
• MDL number: MFCD00008765
• Beilstein/REAXYS Number: 635680
• Assay: ≥99.5% (GC)
• Technique(s): UV/Vis spectroscopy: suitable
• Bp: 56 °C/760 mmHg (lit.)
• Vapor pressure: 184 mmHg ( 20 °C)

Properties

• agency: USP/NF, reag. ISO, reag. Ph. Eur.
• vapor density: 2 (vs air)
• vapor pressure: 184 mmHg ( 20 °C)
• grade: ACS reagent, puriss. p.a.
• assay: ≥99.5% (GC)
• form: liquid
• expl. lim.: 13.2 %
• technique(s): UV/Vis spectroscopy: suitable
• impurities: ≤0.0002% KMnO₄ red. matter (as O), ≤0.0002% benzene, ≤0.0008% free alkali (as NH₃), ≤0.001% aldehydes (as HCHO), ≤0.001% non-volatile matter, ≤0.0015% free acid (as CH₃COOH), ≤0.01% ethanol (GC), ≤0.05% 2-propanol, ≤0.05% methanol, ≤0.2% water (Karl Fischer)
• refractive index: n20/D 1.3580-1.3600, n20/D 1.359 (lit.)
• pH: 5-6 (20 °C, 395 g/L)
• bp: 56 °C/760 mmHg (lit.)
• mp: −94 °C (lit.)
• density: 0.791 g/mL at 25 °C (lit.)
• SMILES string: CC(C)=O
• cation traces: Al: ≤0.5 ppm, B: ≤0.02 ppm, Ba: ≤0.1 ppm, Bi: ≤0.1 ppm, Ca: ≤0.5 ppm, Cd: ≤0.05 ppm, Co: ≤0.01 ppm, Cr: ≤0.02 ppm, Cu: ≤0.02 ppm, Fe: ≤0.1 ppm, K: ≤0.5 ppm, Li: ≤0.1 ppm, Mg: ≤0.1 ppm, Mn: ≤0.01 ppm, Mo: ≤0.1 ppm, Na: ≤0.5 ppm, Ni: ≤0.02 ppm, Pb: ≤0.02 ppm, Sn: ≤0.1 ppm, Sr: ≤0.1 ppm, Zn: ≤0.05 ppm
• format: neat
• InChI: 1S/C3H6O/c1-3(2)4/h1-2H3
• InChI key: CSCPPACGZOOCGX-UHFFFAOYSA-N

Description

General description

Mixtures of TiO₂ (P25) with rare earth oxides (La₂O₃ or Y₂O₃) calcined at 700°C or 650°C have been reported to efficiently photocatalyze oxidation of acetone. Its aldol condensation in vapor-phase has been investigated over MgO promoted with alkali (Li, Na, K and Cs) or alkaline earth (Ca, Sr and Ba) metal ions. It undergoes Aldol condensation in the presence of Mg-Al layered double hydroxides (LDH) as catalysts and Cl^- and/or CO₃^2- as compensating anions to afford diacetone alcohol and mesityl oxide. Enantioselective Aldol condensation of acetone with various isatins in the presence of dipeptides (catalyst) has been described.[1]

Application

Acetone was used in the synthesis of Ga (Gallium)-DOTATATE (where DOTA=1,4,7,10-tetraazacyclo- dodecane -1,4,7,10-tetraacetic acid) chemicals. It may be used in an assay for determination of ester groups in lipids by spectrophotometric methods.[2]

Acetone′s luminesence intensity is dependent upon the solution components . The absorption of UV light by acetone, results in its photolysis and the production of radials .

Safety Information

• pictograms: GHS02,GHS07
• signalword: Danger
• hcodes: H225,H319,H336
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• target_organs: Central nervous system
• supp_hazards: EUH066
• Storage Class: 3 - Flammable liquids
• flash_point_f: 1.4 °F - closed cup
• flash_point_c: -17.00 °C - closed cup
• pcodes: P210 - P233 - P240 - P241 - P280 - P305 + P351 + P338