Conjugate reduction of an enone accompanied by in situ intramolecular aldol condensation was used to construct the tetrasubstituted cyclohexane nucleus of phomactins. Subsequent relay ring-closing metathesis completed the nine-membered ansa bridge of the diterpenoid framework.
Biosynthesis of phomactins: common intermediate phomactatriene and taxadiene.
Tetsuo Tokiwano et al.
Chemical communications (Cambridge, England), (11)(11), 1324-1325 (2004-05-22)
From 2,2'-methylenedifuran to all stereomeric pentadecane-1,3,5,7,9,11,13,15-octols.
M E Schwenter et al.
The Journal of organic chemistry, 66(23), 7869-7872 (2001-11-10)
Synthesis of homogeneous FePt nanoparticles using a nitrile ligand.
Virginie Monnier et al.
Small (Weinheim an der Bergstrasse, Germany), 4(8), 1139-1142 (2008-07-16)
Journal of hazardous materials, 118(1-3), 171-176 (2005-02-22)
Ex situ electrokinetic (EK) bioremediation of a laboratory-prepared pentadecane-contaminated kaolinite was carried out. Extraneous bacteria and ionic nutrients were continuously supplied to the soil specimen by a new electrolyte circulation method, which controlled electrical pH change of electrolyte solution to
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