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704830

Sigma-Aldrich

5-Bromo-2-(tributylstannyl)pyridine

97% (H-NMR)

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About This Item

Empirical Formula (Hill Notation):
C17H30BrNSn
CAS Number:
611168-46-8
Molecular Weight:
447.04
MDL number:
MFCD10699138
UNSPSC Code:
12352103
PubChem Substance ID:
329762483
NACRES:
NA.22

Assay

97% (H-NMR)

form

liquid

refractive index

n20/D 1.535

bp

140-145 °C

density

1.317 g/mL at 25 °C

functional group

bromo

SMILES string

CCCC[Sn](CCCC)(CCCC)c1ccc(Br)cn1

InChI

1S/C5H3BrN.3C4H9.Sn/c6-5-2-1-3-7-4-5;3*1-3-4-2;/h1-2,4H;3*1,3-4H2,2H3;

InChI key

ZQJRPQMEYHJPJK-UHFFFAOYSA-N

Application

5-Bromo-2-(tributylstannyl)pyridine can be used in the synthesis of:
  • 1,10-Phenanthroline based ditopic ligand, which is used to prepare bistable metallic rotaxanes.[1]
  • Donor-acceptor type isomeric platinum(II) complexes exhibiting excellent optoelectronic properties for OLED applications.[2]
  • Pt(II) polymetallayne derived orange phosphorescent polymers applicable in phosphorescent OLEDs (PHOLEDs).[3]

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

EU REACH Annex XVII (Restriction List)

CAS No.

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Certificates of Analysis (COA)

Lot/Batch Number
MKAA0374V
MKAA0374

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Enhancing the electroluminescence performances of novel platinum (ii) polymetallayne-based phosphorescent polymers through employing functionalized Ir III phosphorescent units and facilitating triplet energy transfer
Huang Z, et al.
Royal Society of Chemistry Advances, 5(16), 12100-12110 (2015)
Achieving NIR emission for donor-acceptor type platinum (II) complexes by adjusting coordination position with isomeric ligands
Zhang Y, et al.
Inorganic Chemistry, 57(22), 14208-14217 (2018)
Synthesis of a novel ditopic ligand incorporating directly bonded 1, 10-phenanthroline and 2, 2': 6', 2 ?-terpyridine units.
Gavi?a P and Tatay S.
Tetrahedron Letters, 47(20), 3471-3473 (2006)

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