93094

Triphenylphosphine, polymer-bound

100-200 mesh, extent of labeling: ~1-1.5 mmol/g Capacity (Phosphor)

• Sinónimos: Copolymer of styrene and divinylbenzene, diphenylphosphinated, Diphenylphosphino-polystyrene, Polystyrene crosslinked with divinylbenzene, diphenylphosphinated
• Fórmula lineal: -C₆H₄P(C₆H₅)₂
• Número de CAS: 39319-11-4
• Peso molecular: 262.29
• Número MDL: MFCD00148025
• Código UNSPSC: 12352128
• ID de la sustancia en PubChem: 57653516
• NACRES: NA.22

Propiedades

• Formulario: solid
• idoneidad de la reacción: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reaction type: solution phase peptide synthesis; reagent type: ligand
• Extensión del etiquetado: ~1-1.5 mmol/g Capacity (Phosphor)
• Matriz: crosslinked with 1% DVB
• tamaño de partícula: 100-200 mesh
• grupo funcional: phosphine
• temp. de almacenamiento: 2-8°C
• cadena SMILES: c1ccc(cc1)P(c2ccccc2)c3ccccc3
• InChI: 1S/C18H15P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
• Clave InChI: RIOQSEWOXXDEQQ-UHFFFAOYSA-N

Descripción

Descripción general

Triphenylphosphine, polymer-bound is polystyrene crosslinked with divinylbenzene, widely used in many organic syntheses such as peptide synthesis, heterocycle synthesis, esterification, and total synthesis. It can be easily removed from the reaction products by simple filtration.

Aplicación

Triphenylphosphine, polymer-bound is used as a polymer support to synthesize dipeptides, olefins, aryl-alkyl ethers, and in the esterification of alkylphosphonic acids. It acts as a Lewis acid, and dehydrating agent when complexed with halogen, hence useful in the acetonation of sugars.

Información de seguridad

• Código de clase de almacenamiento: 11 - Combustible Solids
• Clase de riesgo para el agua (WGK): WGK 3
• Equipo de protección personal: dust mask type N95 (US), Eyeshields, Faceshields, Gloves