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Merck

69485

Sigma-Aldrich

Methyltrioctylammonium chloride

≥97.0% (AT)

Sinónimos:

Trioctylmethylammonium chloride

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About This Item

Fórmula lineal:
[CH3(CH2)6CH2]3N(Cl)CH3
Número de CAS:
Peso molecular:
404.16
Beilstein/REAXYS Number:
4039255
EC Number:
MDL number:
UNSPSC Code:
12352116
PubChem Substance ID:
NACRES:
NA.22
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Quality Level

assay

≥97.0% (AT)

impurities

~1% water

SMILES string

[Cl-].CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC

InChI

1S/C25H54N.ClH/c1-5-8-11-14-17-20-23-26(4,24-21-18-15-12-9-6-2)25-22-19-16-13-10-7-3;/h5-25H2,1-4H3;1H/q+1;/p-1

InChI key

XKBGEWXEAPTVCK-UHFFFAOYSA-M

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Application

Methyltrioctylammonium chloride can be used:
  • As a catalyst in the synthesis of acridine dione derivatives from aromatic aldehyde, dimedone and amines under ultrasonic irradiations.[1]
  • As a catalyst in the synthesis of extended π-systems using aromatic aldehydes and methyldiazines.[2]
  • As a component of a catalytic system used in the Suzuki-Miyaura cross-coupling reaction of a variety of aryl and heteroaryl chlorides in H2O.[3]

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Repr. 1B - Skin Corr. 1A - STOT RE 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

235.4 °F

flash_point_c

113 °C

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Quaternary ammonium salt-assisted synthesis of extended pi-systems from methyldiazines and aromatic aldehydes
Vanden E, et al.
Synthetic Communications, 31(20), 3167-3173 (2001)
Xin Di et al.
Journal of separation science, 43(15), 3129-3135 (2020-06-09)
A green extractant, hydrophobic deep eutectic solvent was first introduced for extraction of tetracycline, oxytetracycline, and chlortetracycline from environmental water samples prior to high-performance liquid chromatography determination. Deep eutectic solvents consist of methyltrioctylammonium chloride and various medium-chain alcohols/acids, and are
Methyltrioctylammonium chloride catalysed sonochemical synthesis of acridine diones
Kaur B and Kumar H
Journal of Chemical Sciences (Bangalore), 125(5), 989-992 (2013)
A highly active catalytic system for Suzuki--Miyaura cross-coupling reactions of aryl and heteroaryl chlorides in water
Mao S, et al.
Organic & Biomolecular Chemistry, 10(47), 9410-9417 (2012)
E A El-Sofany
Journal of hazardous materials, 153(3), 948-954 (2007-11-06)
Aliquat-336 in benzene was supported on Amberlite XAD-4 crosslinked polystyrene resin. The use of XAD-4 impregnated with Aliquat-336 resin for removal of lanthanum(III) and gadolinium(III) from nitrate medium was carried out using batch technique. Various parameters affecting the uptake of

Questions

  1. Hi! What gloves are appropriate whilst handling methyltrioctylammonium chloride? The SDS only says gloves are "required" and fails to adress any actual requirements/standards.

    1 answer
    1. The type of gloves recommended to handle this product are KCL 741 Dermatril® L.

      Please refer to section 8.2 of the product Safety Data Sheet for this information.

      Helpful?

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