398799

Dichloro(1,10-phenanthroline)palladium(II)

• Fórmula empírica (notación de Hill): C₁₂H₈Cl₂N₂Pd
• Número de CAS: 14783-10-9
• Peso molecular: 357.53
• MDL number: MFCD00192008
• UNSPSC Code: 12161600
• PubChem Substance ID: 24864767
• NACRES: NA.22

Propiedades

• reaction suitability: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• SMILES string: Cl[Pd]Cl.c1cnc2c(c1)ccc3cccnc23
• InChI: 1S/C12H8N2.2ClH.Pd/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;/h1-8H;2*1H;/q;;;+2/p-2
• InChI key: YGAISFRMWCCXCG-UHFFFAOYSA-L

Descripción

Application

Catalyst for:

• Carbonylation of alkyl nitrites
• Arylation reactions
• Multiple acetylene insertions under Sonogashira reaction protocol
• Cross-coupling reactions of pyridine carboxylic acid chlorides with alkylzinc reagents
• Hydrophosphinylation of alkenes and alkynes
• Heck reaction
• Regioselective and stereoselective aminohalogenation reactions
• Reaction of chloroenynes and chlorodienes with Grignard reagents for the synthesis of stereodefined enynes and dienes

• Affects the aggregation of human prion protein PrP106-126

Información de seguridad

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable