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230995

Sigma-Aldrich

2-(2-Bromoethyl)-1,3-dioxolane

96%

Sinónimos:

3-Bromopropionaldehyde ethylene acetal

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About This Item

Fórmula empírica (notación de Hill):
C5H9BrO2
Número de CAS:
18742-02-4
Peso molecular:
181.03
Beilstein/REAXYS Number:
103516
EC Number:
242-551-1
MDL number:
MFCD00003216
UNSPSC Code:
12352100
PubChem Substance ID:
24853846
NACRES:
NA.22

assay

96%

form

liquid

contains

sodium bicarbonate as stabilizer

refractive index

n20/D 1.479 (lit.)

bp

68-70 °C/8 mmHg (lit.)

density

1.542 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

BrCCC1OCCO1

InChI

1S/C5H9BrO2/c6-2-1-5-7-3-4-8-5/h5H,1-4H2

InChI key

GGZQLTVZPOGLCC-UHFFFAOYSA-N

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General description

Copper-catalyzed borylation of 2-(2-bromoethyl)-1,3-dioxolane with bis(pinacolato)diboron followed by treatment with potassium bifluoride affords the key organotrifluoroborate reagent.

2-(2-Bromoethyl)-1,3-dioxolane is a cyclic ether derivative with a dioxolane ring, used as a building block in organic synthesis and polymer industry.

Application

2-(2-Bromoethyl)-1,3-dioxolane was used:
  • as starting reagent for the synthesis of (5Z,9Z)-5,9-hexadecadienoic acid, (5Z,9Z)-5,9-nonadecadienoic acid and (5Z,9Z)-5,9-eicosadienoic acid
  • in synthesis of 1-deoxy-castanospermine and 1-deoxy-8a-epi-castanospermine
  • in asymmetric total synthesis of both enantiomers of marine mollusk metabolite pulo′upone via Evans′ asymmetric Diels-Alder reaction
  • as alkylating agent for amines, dithianes and carboximides
  • with eynamides and sodium azide in a "one-pot" synthesis of triazoles

pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 2

flash_point_f

149.0 °F - closed cup

flash_point_c

65 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Sigma-Aldrich

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Advanced Synthesis & Catalysis, 348, 2437-2437 (2006)
Nicolas Fleury-Brégeot et al.
Organic letters, 15(7), 1536-1539 (2013-03-16)
A robust and efficient protocol for the introduction of the dioxolanylethyl moiety onto various aryl and heteroaryl halides has been developed, providing cross-coupling yields up to 93%. Copper-catalyzed borylation of 2-(2-bromoethyl)-1,3-dioxolane with bis(pinacolato)diboron followed by treatment with potassium bifluoride provides
Tetrahedron Letters, 34, 6411-6411 (1993)
Tetrahedron Letters, 34, 7705-7705 (1993)
N M Carballeira et al.
Chemistry and physics of lipids, 100(1-2), 33-40 (2000-01-20)
The delta 5,9 fatty acids (5Z,9Z)-5,9-hexadecadienoic acid, (5Z,9Z)-5,9-nonadecadienoic acid, and (5Z,9Z)-5,9-eicosadienoic acid were synthesized for the first time in four steps (9-12% overall yield) starting from commercially available 2-(2-bromoethyl)-1,3-dioxolane. The synthetic approach provided enough material to corroborate the structure and
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