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223050

Sigma-Aldrich

2,4,6-Tri-tert-butylaniline

99%

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About This Item

Fórmula lineal:
[(CH3)3C]3C6H2NH2
Número de CAS:
961-38-6
Peso molecular:
261.45
EC Number:
213-507-9
MDL number:
MFCD00011645
UNSPSC Code:
12352100
PubChem Substance ID:
24853364
NACRES:
NA.22

assay

99%

form

solid

mp

145-147 °C (lit.)

SMILES string

CC(C)(C)c1cc(c(N)c(c1)C(C)(C)C)C(C)(C)C

InChI

1S/C18H31N/c1-16(2,3)12-10-13(17(4,5)6)15(19)14(11-12)18(7,8)9/h10-11H,19H2,1-9H3

InChI key

REJGDSCBQPJPQT-UHFFFAOYSA-N

Categorías relacionadas

Application

2,4,6-Tri-tert-butylnitrobenzene (bulky amine) was used in the synthesis of monomeric iminophosphorane.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Michael D. Mikoluk et al.
Inorganic chemistry, 38(12), 2791-2801 (2001-10-24)
The substituted-exo-phosphine (X = F, NMe(2), OCH(2)CF(3)) diazaphospholephosphines are exclusively oxidized at this center with either chalcogens (S, Se) or azides to phosphoranodiazaphospholes. Oxidation imparts a dramatic upfield shift of the phosphorus NMR signals and an increase in the (1)J(PC)
João Barroso-Batista et al.
Current biology : CB, 30(6), 1049-1062 (2020-03-07)
Members of the gut microbiota are thought to experience strong competition for nutrients. However, how such competition shapes their evolutionary dynamics and depends on intra- and interspecies interactions is poorly understood. Here, we test the hypothesis that Escherichia coli evolution
Ritesh Ranjan Pal et al.
Cell, 177(3), 683-696 (2019-04-02)
Microbiota and intestinal epithelium restrict pathogen growth by rapid nutrient consumption. We investigated how pathogens circumvent this obstacle to colonize the host. Utilizing enteropathogenic E. coli (EPEC), we show that host-attached bacteria obtain nutrients from infected host cell in a process we
Johana Vásquez-Procopio et al.
Metallomics : integrated biometal science, 12(2), 218-240 (2019-12-05)
Manganese is considered essential for animal growth. Manganese ions serve as cofactors to three mitochondrial enzymes: superoxide dismutase (Sod2), arginase and glutamine synthase, and to glycosyltransferases residing in the Golgi. In Drosophila melanogaster, manganese has also been implicated in the

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