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406341

Sigma-Aldrich

Nickel(II) bromide ethylene glycol dimethyl ether complex

97%

Sinónimos:

(1,2-Dimethoxyethane)nickel dibromide, Dibromo(1,2-dimethoxyethane)nickel, Dibromo(1,2-dimethoxyethane)nickel(II)

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About This Item

Fórmula lineal:
NiBr2 · CH3OCH2CH2OCH3
Número de CAS:
28923-39-9
Peso molecular:
308.62
MDL number:
MFCD00013480
UNSPSC Code:
12352302
PubChem Substance ID:
24865368
NACRES:
NA.23

assay

97%

form

powder

reaction suitability

reagent type: catalyst
core: nickel

SMILES string

Br[Ni]Br.COCCOC

InChI

1S/C4H10O2.2BrH.Ni/c1-5-3-4-6-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2

InChI key

VHSVJTYBTJCDFL-UHFFFAOYSA-L

General description

Nickel(II) bromide ethylene glycol dimethyl ether complex, also known as Ni(II) bromide ethylene glycol dimethyl ether complex. It is an organometallic coordination compound used as a precursor for the deposition of nickel-containing thin films. It is also found applications in organic synthesis as a Lewis acid catalyst.

Application

Nickel(II) bromide ethylene glycol dimethyl ether complex can be used as a precursor for synthesizing various nickel(II) complexes. These complexes used as a catalysts for:      
  • The selective transformation of ethylene into higher-order products.     
  • The vinyl polymerization of norbornene.      
  • The preparation of poly(3-hexylthiophene) (P3HT) Kumada catalyst transfer polymerization. It facilitates good control over the molecular weight of the conjugating polymer.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 Inhalation - Flam. Sol. 1 - Muta. 2 - Repr. 2 - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1 Inhalation

target_organs

Respiratory Tract,Skin

Storage Class

4.1B - Flammable solid hazardous materials

wgk_germany

WGK 3

flash_point_f

26.6 °F - Non-equilibrium method

flash_point_c

-3 °C - Non-equilibrium method

ppe

dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Certificados de análisis (COA)

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Rapid flow-based synthesis of poly (3-hexylthiophene) using 2-methyltetrahydrofuran as a bio-derived reaction solvent
Bannock JH, et al.
European Polymer Journal, 80, 240-246 (2016)

Artículos

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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