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100242

Sigma-Aldrich

3-Aminophenol

98%

Sinónimos:

m-Aminophenol

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About This Item

Fórmula lineal:
H2NC6H4OH
Número de CAS:
591-27-5
Peso molecular:
109.13
Beilstein:
636059
Número CE:
209-711-2
Número MDL:
MFCD00007786
Código UNSPSC:
12352100
ID de la sustancia en PubChem:
24846518
NACRES:
NA.22
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Nivel de calidad

200

Ensayo

98%

Formulario

solid

bp

164 °C/11 mmHg (lit.)

mp

120-124 °C (lit.)

cadena SMILES

Nc1cccc(O)c1

InChI

1S/C6H7NO/c7-5-2-1-3-6(8)4-5/h1-4,8H,7H2

Clave InChI

CWLKGDAVCFYWJK-UHFFFAOYSA-N

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Aplicación

3-Aminophenol has been used in the synthesis of disulfonated bis[4-(3-aminophenoxy)phenyl]sulfone (S-BAPS).[1]
It can be used to synthesize:
  • Methyl 2-oxo-7-[(triphenylphosphoranylidene)amino]-2H-chromene-4-carboxylate by reacting with dimethyl acetylenedicarboxylate (DMAD) in the presence of triphenylphosphine.[2]
  • 3-Amino-2-cyclohexen-1-one via palladium-catalyzed hydrogenation.[3]

Pictogramas

Exclamation markEnvironment
GHS07,GHS09

Palabra de señalización

Warning

Frases de peligro

H302 + H332,H319,H411

Clasificaciones de peligro

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2

Código de clase de almacenamiento

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Clase de riesgo para el agua (WGK)

WGK 2

Equipo de protección personal

dust mask type N95 (US), Eyeshields, Gloves

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Certificados de análisis (COA)

Lot/Batch Number
0000231869
MKCT0738
STBK0386
STBJ1605
STBJ0309

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Sijing Chen et al.
Polymers, 11(6) (2019-06-20)
Benzoxazine containing fluorinated aromatic ether nitrile linkage (FAEN-Bz) had been synthesized from 2,6-dichlorobenzonitrile, 4,4'-(hexafluoroisopropylidene)diphenol (bisphenol AF), 3-Aminophenol, formaldehyde, phenol by condensation polymerization and Mannich ring-forming reaction. Structures of the monomer were verified by Proton NMR spectrum (1H-NMR) and Fourier transform
Vinyltriphenylphosphonium salt mediated synthesis of 1, 4-benzoxazine and coumarin derivatives.
Yavari I, et al.
Tetrahedron, 58(34), 6895-6899 (2002)
A Practical and One-Pot Procedure for the Synthesis of 3-Amino-2-cyclohexen-1-one from 3-Aminophenol.
Sajiki H
Organic Process Research & Development, 9(2), 219-220 (2005)
Wenjie Yang et al.
Small (Weinheim an der Bergstrasse, Germany), 16(30), e2002236-e2002236 (2020-06-25)
This research reports gold (Au) and platinum (Pt) nanocatalysts spatially confined in a porous carbon nanosphere as a new solar-driven carbon nanoreactor (CNR). The CNRs have confined size (≈100 nm), high specific surface area, and high thermal and electrical conductivity.
Ping-Chih Hsu et al.
Oncology reports, 42(2), 697-707 (2019-06-25)
Human non‑small cell lung cancer (NSCLC) is associated with an extremely poor prognosis especially for the 40% of patients who develop brain metastasis, and few treatment strategies exist. Cucurbitacin E (CuE), an oxygenated tetracyclic triterpenoid isolated from plants particularly of
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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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