Polymerization of epoxidized triglycerides with fluorosulfonic acid: The article investigates the use of fluorosulfonic acid for the cationic polymerization of epoxidized triglycerides, exploring its potential in polymer chemistry (Biswas et al., 2016).
Photoelectrochemical (PEC) water vapor splitting by using n-type semiconductor electrodes with a proton exchange membrane (PEM) enabled pure hydrogen production from humidity in ambient air. We proved a design concept that the gas-electrolyte-semiconductor triple-phase boundary on a nanostructured photoanode is
Chemical & pharmaceutical bulletin, 45(6), 1085-1088 (1997-06-01)
In order to develop novel methods for electrophilic and enantioselective fluorination of active methine compounds, preliminary experiments were carried out. The N-tosyl derivative 5 obtained from D-phenylglycine was fluorinated with FClO3 or diluted F2 gas to give the N-fluoro-N-tosyl derivative
Archives of biochemistry and biophysics, 240(2), 509-523 (1985-08-01)
The kinetics of the forward ATP sulfurylase-catalyzed reaction were examined using a new assay based on 32PPi released from [gamma-32P]MgATP in the presence of inorganic sulfate. Replots yielded Vmaxf = 6.6 units mg protein-1, KmA = 0.13 mM, Kia =
The Journal of biological chemistry, 262(34), 16279-16288 (1987-12-05)
ATP sulfurylase from Penicillium chrysogenum is a noncooperative homooligomer containing three free sulfhydryl groups per subunit. Under nondenaturing conditions, one SH group per subunit was modified by 5,5'-dithiobis-(2-nitrobenzoate), or N-ethylmaleimide. Modification had only a small effect on kcat, but markedly
Using a novel, acid-mediated cyclization methodology, a direct access to Cetalox ((+/-)-1; a commercially important ambergris-type odorant) and various structurally related didehydro (i.e., 19, 26, and 30) and tetradehydro (i.e., 28 and 37/38) analogues is described. Treatment of either (E,E)-14
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