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339741

Sigma-Aldrich

Sulfuric acid

99.999%

Synonym(s):

Dihydrogen sulfate, Oil

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About This Item

Linear Formula:
H2SO4
CAS Number:
Molecular Weight:
98.08
Beilstein:
2037554
EC Number:
MDL number:
UNSPSC Code:
12352301
PubChem Substance ID:
NACRES:
NA.22

Agency

suitable for SM 5210

Quality Level

vapor density

<0.3 (25 °C, vs air)

vapor pressure

1 mmHg ( 146 °C)

description

Nominally 95-98% H2SO4

Assay

99.999%

form

viscous liquid

color

clear

pH

1.2 (5 g/L)

bp

~290 °C (lit.)

density

1.840 g/mL at 25 °C (lit.)

SMILES string

OS(O)(=O)=O

InChI

1S/H2O4S/c1-5(2,3)4/h(H2,1,2,3,4)

InChI key

QAOWNCQODCNURD-UHFFFAOYSA-N

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General description

Sulfuric acid is a strong mineral acid, that is commonly used in organic synthesis as a reagent, catalyst, and solvent. It is also useful to perform several functions, including dehydration, sulfonation, and nitration.

Application

Sulfuric acid is used:
  • As a catalyst in the esterification of acetic and palmitic acid.
  • As a solvent in the synthesis of binary technetium sulfide via the reaction of pertechnetate and hydrogen sulfide.
  • As a dehydrating agent, catalyst, and active reactant in the chemical industry.
  • To prepare silica-sulfuric acid composite, which is used as a catalyst in organic synthesis.

Analysis Note

Purity based on trace metals

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Analysis of Malondialdehyde, Chlorophyll Proline, Soluble Sugar, and Glutathione Content in Arabidopsis seedling
Zhang Z, et al.
Bio-protocol, 3(14) (2013)
The Mechanical Performance of a Biomimetic Nanointerface Made of Multilayered Polyelectrolytes.
Cavelier S, et al.
European Journal of Inorganic Chemistry, 32, 5380-5389 (2012)
Esterification of free fatty acids using sulfuric acid as catalyst in the presence of triglycerides
Marchetti JM and Errazu AF
Biomass and Bioenergy, 32(9), 892-895 (2008)
Silica sulfuric acid and silica chloride as efficient reagents for organic reactions
Salehi P, et al.
Current Organic Chemistry, 10(17), 2171-2189 (2006)
Preparation of activated carbons previously treated with sulfuric acid: a study of their adsorption capacity in solution
Cuerda-Correa EM, et al.
Applied Surface Science, 252(17), 6042-6045 (2006)

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