Skip to Content
Merck
All Photos(3)

Key Documents

View All Documentation

908541

Sigma-Aldrich

Ni(IPr*OMe)(phenyl acrylate)2

Synonym(s):

Montgomery Ni catalyst

Sign Into View Organizational & Contract Pricing
All Photos(3)

About This Item

Empirical Formula (Hill Notation):
C87H72N2NiO6
CAS Number:
2230140-52-8
Molecular Weight:
1300.21
UNSPSC Code:
12352103
NACRES:
NA.22

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

Application

Ni(IPr*OMe)(phenyl acrylate)2 is an NHC-Ni(0) precatalyst developed in the Montgomery lab used for a variety of synthetic transformations including reductive couplings of aldehydes and alkynes and N-arylation of amines.

Other Notes

Stable, Well-Defined Nickel(0) Catalysts for Catalytic C–C and C–N Bond Formation

related product

Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Alex J Nett et al.
ACS catalysis, 8(7), 6606-6611 (2018-08-07)
The synthesis and catalytic activity of several classes of NHC-Ni(0) pre-catalysts stabilized by electron-withdrawing alkenes are described. Variations in the structure of fumarate and acrylate ligands modulate the reactivity and stability of the NHC-Ni(0) pre-catalysts and lead to practical and

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service