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155721

Sigma-Aldrich

Methacrylic acid

contains 250 ppm MEHQ as inhibitor, 99%

Synonym(s):

2-Methacrylic acid, 2-Methylpropenoic acid

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5 G
€17.80
100 G
€51.00
500 G
€62.70
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€199.00
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€243.00
18 KG
€702.00

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5 G
€17.80
100 G
€51.00
500 G
€62.70
2 KG
€199.00
3 KG
€243.00
18 KG
€702.00

About This Item

Linear Formula:
H2C=C(CH3)COOH
CAS Number:
Molecular Weight:
86.09
Beilstein:
1719937
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23
pH:
2.0-2.2 (20 °C, 100 g/L)

€17.80


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vapor density

>3 (vs air)

Quality Level

vapor pressure

1 mmHg ( 20 °C)

Assay

99%

form

liquid

autoignition temp.

752 °F

contains

250 ppm MEHQ as inhibitor

refractive index

n20/D 1.431 (lit.)

pH

2.0-2.2 (20 °C, 100 g/L)

bp

163 °C (lit.)

mp

12-16 °C (lit.)

density

1.015 g/mL at 25 °C (lit.)

SMILES string

C=C(C)C(O)=O

InChI

1S/C4H6O2/c1-3(2)4(5)6/h1H2,2H3,(H,5,6)

InChI key

CERQOIWHTDAKMF-UHFFFAOYSA-N

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General description

Methacrylic acid (MAA) is an organic compound, colorless, viscous liquid. It is a monofunctional methacrylayte monomer.[1] It is soluble in warm water and miscible in most organic solvents. MAA is used as a starting material for the production of its esters, especially methyl methacrylate and poly methyl methacrylate (PMMA).[2]

Application

MAA is used to synthesize poly(methacrylic acid)-g-poly(ε-caprolactone) copolymers,[3] polymeric blends with PMMA[4] and hydroxyethyl methacrylate (HEMA)-MAA hydrogels.

Pictograms

Skull and crossbonesCorrosion

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

Flash Point(F)

152.6 °F - closed cup

Flash Point(C)

67 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Synthesis of graft copolymers of poly(methacrylic acid)-g-poly(?-caprolactone) by coupling ROP and RAFT polymerizations
Kiehl J, et al.
Polymer, 53(3), 694-700 (2012)
Reversible Addition Fragmentation Chain Transfer
(RAFT) Polymerization
Moad G, et al.
Material Matters, 5(1) (2010)
Josué A Torres-Ávalos et al.
Polymers, 13(4) (2021-03-07)
Design of a smart drug delivery system is a topic of current interest. Under this perspective, polymer nanocomposites (PNs) of butyl acrylate (BA), methacrylic acid (MAA), and functionalized carbon nanotubes (CNTsf) were synthesized by in situ emulsion polymerization (IEP). Carbon
Thomas J Dursch et al.
Biomaterials, 35(2), 620-629 (2013-10-24)
Two-photon confocal microscopy and back extraction with UV/Vis-absorption spectrophotometry quantify equilibrium partition coefficients, k, for six prototypical drugs in five soft-contact-lens-material hydrogels over a range of water contents from 40 to 92%. Partition coefficients were obtained for acetazolamide, caffeine, hydrocortisone
Macro-micro relationship in nanostructured functional
Composites
Zanotto A, et al.
Express Polymer Letters, 6(5), 410-416 (2012)

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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