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682500

Sigma-Aldrich

Copper(I) thiophene-2-carboxylate

Sinónimos:

Cu (TC)

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1 G
MXP 2,865.00

MXP 2,865.00

Disponible para envío el21 de abril de 2025Detalles

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1 G
MXP 2,865.00

About This Item

Fórmula empírica (notación de Hill):
C5H3CuO2S
Número de CAS:
68986-76-5
Peso molecular:
190.69
Número MDL:
MFCD02183524
Código UNSPSC:
12161600
ID de la sustancia en PubChem:
24885718
NACRES:
NA.22

MXP 2,865.00

Disponible para envío el21 de abril de 2025Detalles

Solicitar un pedido a granel

Formulario

solid

Nivel de calidad

100

idoneidad de la reacción

core: copper
reaction type: C-C Bond Formation
reagent type: catalyst

cadena SMILES

[Cu]OC(=O)c1cccs1

InChI

1S/C5H4O2S.Cu/c6-5(7)4-2-1-3-8-4;/h1-3H,(H,6,7);/q;+1/p-1

Clave InChI

SFJMFSWCBVEHBA-UHFFFAOYSA-M

Categorías relacionadas

Aplicación

Copper(I) thiophene-2-carboxylate can be used as a reactant or reagent in:
  • Studies of xenobiotic response to herbicide safener derivatives.[1]
  • Synthesis of functionalized BODIPY dye analogs.[2]
  • Orthogonal cross-coupling reactions.[3]
  • Preparation of parent borondipyrromethene system.[4]
  • Copper mediated cross-coupling.[5][6]

Reactant or reagent involved in:
  • Studies of xenobiotic response to herbicide safener derivatives
  • Synthesis of functionalized BODIPY dye analogs
  • Orthogonal cross-coupling reactions
  • Preparation of parent borondipyrromethene system
  • Copper mediated cross-coupling

Pictogramas

Environment
GHS09

Palabra de señalización

Warning

Frases de peligro

H410

Consejos de prudencia

P273 - P391 - P501

Clasificaciones de peligro

Aquatic Acute 1 - Aquatic Chronic 1

Código de clase de almacenamiento

11 - Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

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Certificados de análisis (COA)

Lot/Batch Number
MKCP0766
MKCQ5564
MKCJ9381
MKCD4033
MKBX2582V

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N-Amidation by copper-mediated cross-coupling of organostannanes or boronic acids with O-acetyl hydroxamic acids.
Zhang Z, et al.
Organic Letters, 10(14), 3005-3008 (2008)
Xenobiotic responsiveness of Arabidopsis thaliana to a chemical series derived from a herbicide safener.
Skipsey M, et al.
The Journal of Biological Chemistry, 286(37), 32268-32276 (2011)
2?and 3?Monohalogenated BODIPY Dyes and Their Functionalized Analogues: Synthesis and Spectroscopy.
Leen V, et al.
European Journal of Organic Chemistry, 2011(23), 4386-4396 (2011)
Regioselective Syntheses of 2, 3?Substituted Pyridines by Orthogonal Cross?Coupling Strategies.
Koley M, et al.
European Journal of Organic Chemistry, 2011(10), 1972-1979 (2011)
Zhihui Zhang et al.
Organic letters, 8(19), 4331-4333 (2006-09-08)
A new method for the synthesis of nitriles is described. As a complement to the classic cyanation of aryl halides using cyanide sources and a transition metal catalyst, the palladium-catalyzed cross-coupling of thiocyanates with boronic acids in the presence of
Ver todos los artículos relacionados

Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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