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Merck

338001

Sigma-Aldrich

Zirconium(IV) acetylacetonate

97%

Sinónimos:

2,4-Pentanedione zirconium(IV) derivative, Tetrakis(2,4-pentanedionato)zirconium(IV), Zirconium(IV) 2,4-pentanedionate

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100 G
MXP 57,589.00

MXP 57,589.00


Disponible para envío el21 de abril de 2025Detalles


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100 G
MXP 57,589.00

About This Item

Fórmula lineal:
Zr(C5H7O2)4
Número de CAS:
Peso molecular:
487.66
Beilstein:
4160373
Número CE:
Número MDL:
Código UNSPSC:
12352103
ID de la sustancia en PubChem:
NACRES:
NA.23

MXP 57,589.00


Disponible para envío el21 de abril de 2025Detalles


Solicitar un pedido a granel

Nivel de calidad

Ensayo

97%

Formulario

powder

idoneidad de la reacción

core: zirconium
reagent type: catalyst

cadena SMILES

CC(=O)\C=C(\C)O[Zr](O\C(C)=C/C(C)=O)(O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/4C5H8O2.Zr/c4*1-4(6)3-5(2)7;/h4*3,6H,1-2H3;/q;;;;+4/p-4/b4*4-3-;

Clave InChI

FPFOSIXCIBGKOH-MTOQALJVSA-J

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Descripción general

Zirconium(IV) acetylacetonate is a white crystalline organometallic solid widely used as a sol-gel precursor to synthesize Zirconium-based nanomaterials and thin films. It also finds application in the field of catalysis and polymer synthesis.

Aplicación

Zirconium(IV) acetylacetonate can be used:
  • As a sol-gel precursor to synthesize zirconia nanoparticles with photocatalytic activity.[1]
  • As an additive to improve the performance of the electron transport layer in perovskite solar cells.[2]
  • To synthesize as-prepared zirconium acetylacetonate (a-ZrAcac) film as a cathode buffer layer in polymer solar cells. It exhibited an average power conversion efficiency (PCE) of 8.75% which is significantly improved than that of the devices with traditional Ca/Al cathode.[3]
  • To synthesize high-κ zirconium oxide gate dielectric for Organic Field-Effect Transistors at low voltage operation.[4]
  • To fabricate the conductive interlayers for quantum dot light-emitting devices(QLEDs), which enhances quantum efficiency, power efficiency, and longer operational lifetimes.[5]
  • As a ring-opening initiator to synthesize biodegradable polyacids.[6]
  • As a catalyst to synthesize polylactide terpolymers.[7]

Pictogramas

FlameExclamation mark

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Acute Tox. 4 Oral - Flam. Sol. 1

Código de clase de almacenamiento

4.1B - Flammable solid hazardous materials

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

dust mask type N95 (US), Eyeshields, Gloves


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Certificados de análisis (COA)

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Los clientes también vieron

Synthesis and properties of polylactide terpolymers P(LLA-TMC-GA) catalyzed by zirconium(IV)acetylacetonate
Shaohua Wen, et al
Applied Organometallic Chemistry, 32, e4177-e4177 (2018)
High performance polymer solar cells with as-prepared zirconium acetylacetonate film as cathode buffer layer
Zhan'ao Tan, et al.
Scientific Reports, 4, 4691-4691 (2014)
Zirconium (IV) acetylacetonate: Ring-opening initiator mediating one-step synthesis of biodegradable polyacids
Piotr Dobrzy'nski, et al.
Advances in Polymer Technology, 2019-2019 (2019)
Improving the TiO2 electron transport layer in perovskite solar cells using acetylacetonate-based additives
Hsin-Hua Wang, et al.
Journal of Materials Chemistry, 3, 9108-9115 (2015)
Room-temperature fabrication of ultrathin oxide gate dielectrics for low-voltage operation of organic field-effect transistors
Young Min Park, et al.
Advanced Materials, 23, 971-974 (2011)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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