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296945

Sigma-Aldrich

Sodium cyanoborohydride solution

5.0 M in 1 M NaOH

Sinónimos:

Sodium borocyanohydride, Sodium cyanoborohydride, Sodium cyanotrihydroborate

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About This Item

Fórmula lineal:
NaBH3CN
Número de CAS:
25895-60-7
Peso molecular:
62.84
MDL number:
MFCD00003516
UNSPSC Code:
12352306
PubChem Substance ID:
24857889
NACRES:
NA.22

reaction suitability

reagent type: reductant

concentration

5.0 M in 1 M NaOH

density

1.083 g/mL at 25 °C

SMILES string

[Na+].[H][B-]([H])([H])C#N

InChI

1S/CH3BN.Na/c2-1-3;/h2H3;/q-1;+1

InChI key

CVDUGUOQTVTBJH-UHFFFAOYSA-N

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Categorías relacionadas

General description

Sodium cyanoborohydride is a selective, mild reducing reagent for a number of functional groups such as aldehydes, ketones, acetals, epoxides and imines.

Application

Reactant for:
  • Direct conversion of heterocyclic aldehydes to esters (oxidizing behavior)
  • Reductive amination reactions
  • Intramolecular reductive cyclization reactions
  • Reductions reactions
  • Preparation of dicyanoborate-based ionic liquids as hypergolic fluids for bipropellants

signalword

Danger

Hazard Classifications

Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

supp_hazards

EUH032

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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e-EROS Encyclopedia of Reagents for Organic Synthesis (2016)
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We report here that unprotected carbohydrates (maltose, lactose, cellobiose, and maltoheptaose) can be attached to the aminoalkylated oligonucleotides under mild reductive-amination conditions (aqueous borate buffer, pH 8.0, NaBH(3)CN, 60 degrees C) without notable side reactions. Quadruplex-forming G-rich oligonucleotide, 5'-aminoalkyl d(TGGGGT)
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