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Merck

282782

Sigma-Aldrich

Platinum(II) acetylacetonate

97%

Sinónimos:

2,4-Pentanedione platinum(II) derivative, Pt(acac)2

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500 MG
MXP 3,055.00
5 G
MXP 15,262.00

MXP 3,055.00


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500 MG
MXP 3,055.00
5 G
MXP 15,262.00

About This Item

Fórmula lineal:
Pt(C5H7O2)2
Número de CAS:
Peso molecular:
393.29
Beilstein:
4136189
Número CE:
Número MDL:
Código UNSPSC:
12352103
ID de la sustancia en PubChem:
NACRES:
NA.23

MXP 3,055.00


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Nivel de calidad

Ensayo

97%

Formulario

solid

idoneidad de la reacción

core: platinum
reagent type: catalyst

mp

249-252 °C (lit.)

cadena SMILES

CC(=O)\C=C(\C)O[Pt]O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.Pt/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;

Clave InChI

KLFRPGNCEJNEKU-FDGPNNRMSA-L

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Descripción general

Platinum(II)acetylacetonate is widely used as a Ptsource and precursor in the preparation of nanocatalysts and films. It is alsoused as a catalyst in N-allylation reactions.

Aplicación

Platinum(II)acetylacetonate can be used as an efficient catalyst:
  • In the preparation of N-allylanilines by the direct use of allylic alcohols. Anilines with electron-donating groups give good yields.
  • For selective N-allylation of 2,3-disubstituted indoles in water.
Pt-loaded ZnO thick films can be prepared by flame spray pyrolysis method using zinc naphthenate and platinum(II) acetylacetonate as precursors. These sensing films can be used for acetylene detection and show good selectivity towards carbon monoxide, hydrogen, and methane.

It can be used as a starting material in the preparation of platinum-lead nanoparticles supported on carbon. The PtPb/C catalyst exhibits enhanced electrochemical activity towards methanol and formic acid oxidation.

Pictogramas

Health hazardExclamation mark

Palabra de señalización

Warning

Clasificaciones de peligro

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3

Órganos de actuación

Respiratory system

Código de clase de almacenamiento

11 - Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Chemistry Letters (Jpn), 33, 658-659 (2004)
Xiaochen Shen et al.
Nature communications, 9(1), 4485-4485 (2018-10-28)
Understanding the growth pathway of faceted alloy nanoparticles at the atomic level is crucial to morphology control and property tuning. Yet, it remains a challenge due to complexity of the growth process and technical limits of modern characterization tools. We
Jin Wang et al.
Nanoscale research letters, 14(1), 11-11 (2019-01-10)
Electrochemical sensors have the high sensitivity, fast response, and simple operation for applications in biological, medical, and chemical detection, but limited by the poor stability and high cost of the electrode materials. In this work, we used PtNi lagged-like nanowire
Chemistry of Materials, 18, 6414-6414 (2006)
Chemistry of Materials, 16, 2363-2368 (2004)

Artículos

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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. What is the shelf life for Platinum acetylacetonate? In how much time it normally expires? How it should be stored?

    1 answer
    1. The composition information for this product is considered proprietary. However, upon review of the literature is does appear unlikely.

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