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416681

Sigma-Aldrich

Bis(cyclopentadienyl)titanium(IV) bis(trifluoromethanesulfonate)

98%

Synonym(s):

Bis(cyclopentadienyl)di(triflato)titanium, Di(cyclopentadienyl)titanium(IV) bis(trifluoromethanesulfonate), Titanocene bis(trifluoromethanesulfonate), Titanocene ditriflate

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About This Item

Empirical Formula (Hill Notation):
C12H10F6O6S2Ti
CAS Number:
Molecular Weight:
476.19
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22

Assay

98%

reaction suitability

core: titanium
reagent type: catalyst

SMILES string

[Ti++].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F

InChI

1S/2C5H5.2CHF3O3S.Ti/c2*1-2-4-5-3-1;2*2-1(3,4)8(5,6)7;/h2*1-5H;2*(H,5,6,7);/q;;;;+2/p-2

InChI key

ARUXRBUQJOYABI-UHFFFAOYSA-L

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Application

Catalyst for:
  • Transesterification
  • Stereoselective carbonyl-ene cyclization reactions
  • Sakurai reactions
  • Mukaiyama cross-aldol reactions

Reactant for synthesis of heterobimetallic bridging dinitrogen complexes

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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