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Key Documents

274631

Sigma-Aldrich

1,2,2,6,6-Pentamethylpiperidine

97%

Synonym(s):

PMP, Pempidine

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About This Item

Empirical Formula (Hill Notation):
C10H21N
CAS Number:
Molecular Weight:
155.28
Beilstein:
103806
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

form

liquid

refractive index

n20/D 1.460 (lit.)

bp

187-188 °C (lit.)

density

0.858 g/mL at 25 °C (lit.)

SMILES string

CN1C(C)(C)CCCC1(C)C

InChI

1S/C10H21N/c1-9(2)7-6-8-10(3,4)11(9)5/h6-8H2,1-5H3

InChI key

XULIXFLCVXWHRF-UHFFFAOYSA-N

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General description

The focal 1,8-naphthalimide fluorophores in the antennae were modified with 1,2,2,6,6-pentamethylpiperidine to improve their photostability.

Application

1,2,2,6,6-Pentamethylpiperidine (PMP) was used as an organic structure directing agent (OSDA) in the synthesis of the RTH-type zeolites.

Pictograms

FlameSkull and crossbones

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

131.0 °F - closed cup

Flash Point(C)

55 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Nikolai I Georgiev et al.
Journal of fluorescence, 21(1), 51-63 (2010-07-20)
This paper reports on the divergent synthesis, photophysical properties and photodegradation of novel PAMAM dendrons, core and peripherally functionalized with 1,8-naphthalimide fluorophores. The novel compounds were configured as light-harvesting antennae where the system surface is labeled with blue emitting 4-allyloxy-1,8-naphthalimide
Ming Liu et al.
Physical chemistry chemical physics : PCCP, 16(9), 4155-4164 (2014-01-24)
In addition to the original preparation route of the RTH-type zeolites using 1,2,2,6,6-pentamethylpiperidine (PMP) as an organic structure directing agent (OSDA), we have found that simpler organic amines such as N-methylpiperidine and pyridine can be used as alternative OSDAs in
M L Kemel et al.
Proceedings of the National Academy of Sciences of the United States of America, 86(22), 9006-9010 (1989-11-01)
By use of a sensitive in vitro microsuperfusion method, the cholinergic prsynaptic control of dopamine release was investigated in a prominent striosome (areas poor in acetylcholinesterase activity) located within the core of cat caudate nucleus and also in adjacent matrix
Paul Touboul et al.
European heart journal, 24(16), 1481-1487 (2003-08-16)
Dronedarone, a benzofurane derivative without iodine substituents, shares the electrophysiologic properties of amiodarone. This study was designed to determine the most appropriate dose of dronedarone for prevention of atrial fibrillation (AF) after cardioversion. Patients with persistent AF were randomly allocated
Dean A Myers et al.
Behavioural brain research, 161(1), 39-44 (2005-05-21)
Corticosterone (CORT) micropellets were stereotaxically placed bilaterally at the dorsal margin of the central nucleus of the amygdala (CeA). Both behavioral and physiological responses were recorded (plus maze and colonic discomfort) at 7 days post-implantation. Corticosterone reduced the exploration of

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