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Merck
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文件

902225

Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6

≥95%

别名:

Photocatalyst

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About This Item

经验公式（希尔记法）:
C36H22F16IrN4P
分子量:
1037.75
分類程式碼代碼:
41141700
NACRES:
NA.22

應用

Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 (901466) and supersilanol (902489).

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

其他說明

A radical approach to the copper oxidative addition problem:Trifluoromethylation of bromoarenes

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产品编号
说明
价格

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(Ir[dF(CF3)ppy]2(dtbpy))PF6

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[Ir{dFCF3ppy}2（bpy）]PF6

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Ir(dFppy)3

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铱 [ p -F (t-Bu)-ppy] 3

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Ir(p-F-ppy)3

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Mes -Umemoto 试剂, ≥95%

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[Ir(dFppy)2(dtbbpy)]PF6

901409

[铱 (dF (Me) ppy)] 2 (dtbbpy) ] PF 6

902217

Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%

902489

三（三甲基甲硅烷基）硅烷醇, ≥95%

904694

Ir(p-CF3-ppy)3, ≥95%

905518

Ir(dFFppy)2(dtbbpy)PF6

905917

(Ir[Me(Me)ppy]2(dtbpy))PF6

908568

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6, ≥95%

908703

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6, ≥95%

911607

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6 , ≥95%

912948

Ir[FCF3(CF3)ppy]2(dtbbpy)PF6

922897

[Ir(ppy)2(5,5′-Me2bpy)]PF6, ≥95%

925497

[Ir(dFOMeppy)2(dtbbpy)]PF6, ≥95%

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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分析证书(COA)

Lot/Batch Number
MKCJ9415

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Chip Le et al.
Science (New York, N.Y.), 360(6392), 1010-1014 (2018-06-02)
Transition metal-catalyzed arene functionalization has been widely used for molecular synthesis over the past century. In this arena, copper catalysis has long been considered a privileged platform due to the propensity of high-valent copper to undergo reductive elimination with a

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