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Merck
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文件

905518

Sigma-Aldrich

Ir(dFFppy)2(dtbbpy)PF6

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About This Item

经验公式（希尔记法）:
C40H34F12IrN4P
CAS号:
2042201-18-1
分子量:
1021.90
分類程式碼代碼:
12161600
NACRES:
NA.22

形狀

solid

反應適用性

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

活化光觸媒

465 nm

SMILES 字串

FC1=C(C2=NC=C(F)C=C2)C([Ir]3([N]4=CC=C(C(C)(C)C)C=C4C5=CC(C(C)(C)C)=CC=[N]53)C6=CC(F)=CC(F)=C6C7=CC=C(F)C=N7)=CC(F)=C1.FP(F)(F)(F)(F)F

相关类别

應用

Ir(dFFppy)2(dtbbpy)PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

其他說明

Metallaphotoredox-catalysed sp3–sp3cross-coupling of carboxylic acids with alkyl halides

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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Craig P Johnston et al.
Nature, 536(7616), 322-325 (2016-08-19)
In the past 50 years, cross-coupling reactions mediated by transition metals have changed the way in which complex organic molecules are synthesized. The predictable and chemoselective nature of these transformations has led to their widespread adoption across many areas of

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