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86879

Supelco

四丁基六氟磷酸铵

for electrochemical analysis, ≥99.0%

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About This Item

线性分子式:
(CH3CH2CH2CH2)4N(PF6)
CAS号:
3109-63-5
分子量:
387.43
Beilstein:
4056584
EC 号:
221-472-6
MDL编号:
MFCD00011748
UNSPSC代码:
26111700
PubChem化学物质编号:
329769335
NACRES:
NB.61
价格与库存信息目前不能提供

质量水平

100

方案

≥99.0% (CHN)
≥99.0%

表单

solid

mp

244-246 °C (lit.)

溶解性

acetonitrile: 0.1 g/mL, clear, colorless

SMILES字符串

F[P-](F)(F)(F)(F)F.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.F6P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-7(2,3,4,5)6/h5-16H2,1-4H3;/q+1;-1

InChI key

BKBKEFQIOUYLBC-UHFFFAOYSA-N

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相关类别

一般描述

四丁基铵六氟磷酸盐（TBAHFP）是季铵盐，主要用作电解质。它可溶于液体二氧化硫和二氯甲烷等溶剂。
访问我们的传感器应用门户网站了解更多信息。

应用

TBAHFP 已用于制备聚-3-甲基噻吩与 γ-环糊精（P3MT/γ-CD）电极结合，使用电化学合成方法。[1]

其他说明

非常稳定的、可溶于有机溶液的支持电解质[2]

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H302,H315,H319

危险分类

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCM8532
BCCL4925
BCCL1097
BCCK6470
BCCH7900

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Bouchta D
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M.M. Baizer
Organic Electrochemistry null
Md Khairul Hoque et al.
Frontiers in chemistry, 8, 593932-593932 (2020-11-27)
Nitrogen-free amorphous carbon thin films prepared via sputtering followed by graphitization, were used as precursor materials for the creation of N-doped carbon electrodes with varying degrees of amorphization. Incorporation of N-sites was achieved via nitrogen plasma treatments which resulted in
Ting-Ting Li et al.
ChemSusChem, 12(11), 2402-2408 (2019-05-10)
A RuII complex [Ru(PO3 Et2 -ph-tpy)(6-mbpy)(NCCH3 )]2+ [PO3 Et2 -ph-tpy=diethyl(4-[(2,2':6',2''-terpyridin)-4'-yl]phenyl)phosphonate; 6-mbpy=6-methyl-2,2'-bipyridine] is explored as a molecular catalyst for electrocatalytic CO2 reduction in both a homogeneous solution and, as a phosphonated derivative, on nanocrystalline-TiO2 surfaces. In CH3 CN, the complex acts
Sonia Bruña et al.
Dalton transactions (Cambridge, England : 2003), 43(35), 13187-13195 (2014-07-17)
Reaction of Fe3(CO)12 with 1,2-dithiolene HSC6H2Cl2SH affords a mixture of complexes [Fe2(CO)6(μ-SC6H2Cl2S)] 1, [Fe2(SC6H2Cl2S)4] 2 and [Fe3(CO)7(μ3-SC6H2Cl2S)2] 3. In the course of the reaction the trimetallic cluster 3 is first formed and then converted into the known dinuclear compound 1
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Questions

1–3 of 3 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. I would like to use this product into the glovebox. I didn't open the bottle yet but, as the package does not have the legend ARGON SEALED, I do not know if I can put in directly into the glovebox or how can I proceed (dry in vacuum oven, for example).

    1 answer

    1. This product is not packaged under an inert gas, such as argon or nitrogen. The most common practice when using this type of material in a glove box environment is to transfer a smaller amount of the reagent to a vial or flask and dry it under a vacuum, prior to introducing the glovebox.

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