推荐产品
等級
for GC derivatization
品質等級
形狀
solution
品質
LiChropur™
for esterification of fatty acids for GC purposes
反應適用性
reagent type: derivatization reagent
reaction type: Alkylations
濃度
~10% in 1-butanol (∼1.3 M)
技術
gas chromatography (GC): suitable
密度
0.87 g/mL at 20 °C
儲存溫度
2-8°C
SMILES 字串
FB(F)F
InChI
1S/BF3/c2-1(3)4
InChI 密鑰
WTEOIRVLGSZEPR-UHFFFAOYSA-N
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應用
Learn more in the Product Information
Boron trifluoride-1-butanol solution may be used as a derivatization agent in the separation and identification of water‐soluble low‐molecular‐weight carboxylic acids using capillary electrophoresis (CE) and gas chromatography coupled with mass spectrometry (GC-MS).
Reagent for the esterification of carboxylic acids for GC analysis
法律資訊
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
訊號詞
Danger
危險分類
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A - STOT SE 3
標靶器官
Central nervous system, Respiratory system
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 1
閃點（°F）
95.0 °F - closed cup
閃點（°C）
35 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Capillary electrophoresis determinative and GC-MS confirmatory method for water-soluble organic acids in airborne particulate matter and vehicle emission.
Dabek-Zlotorzynska E, et al.
Journal of Separation Science, 28(13), 1520-1528 (2005)
Casey R Wade et al.
Chemical communications (Cambridge, England), 46(34), 6380-6381 (2010-08-07)
The presence of a proximal cationic group in zwitterionic aryltrifluoroborates such as o-(Ph(2)MeP)C(6)H(4)(BF(3)) stabilizes these compounds against hydrolysis.
Ramanathan Rajaganesh et al.
Carbohydrate research, 345(12), 1649-1657 (2010-06-29)
BF(3).Et(2)O-catalysed O-glycosylation of 1,2,3-tri-O-acetyl-4,6-O-butylidene- and ethylidene-beta-d-glucopyranose with different aliphatic and aromatic alcohols proceeds for the most part with complete retention of anomeric configuration. Antioxidant activity of O-glycosides shows significant inhibition (IC(50) approximately 77%). 1,3-Dipolar cycloaddition of terminal alkyne derivatives of
Bandna et al.
Natural product research, 23(15), 1445-1450 (2009-10-08)
Acylation of beta-caryophyllene, a sesquiterpene hydrocarbon with acetic anhydride, was carried out under mild catalytic conditions using Lewis acids such as BF3.Et2O, ZnCl2, FeCl3, I2 and AlCl3 as catalysts. Among these, BF3.Et2O was found to catalyse the reaction most efficiently
Joanna E Rode et al.
Chirality, 24(1), 5-16 (2011-12-06)
Stabilization energies of the electron donor-acceptor sulfinimine···BF(3) complexes calculated at either the B3LYP/aug-cc-pVTZ or the MP2/aug-cc-pVTZ level do not allow to judge, whether the N- or O-atom in sulfinimine is stronger electron-donor to BF(3) . The problem seems to be
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