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Merck
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文件

72240

Sigma-Aldrich

铝镍合金

purum, 50% Al basis, 50% Ni basis

别名:

Raney® 镍合金, 镍铝合金

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About This Item

CAS号:
12635-27-7
MDL號碼:
MFCD00167392
分類程式碼代碼:
12161600
PubChem物質ID:
329763924
NACRES:
NA.22

品質等級

100

等級

purum

形狀

powder

成份

Al, 50%
Ni, 50%

反應適用性

core: nickel
reagent type: catalyst

SMILES 字串

[Al].[Ni]

InChI

1S/Al.Ni

InChI 密鑰

NPXOKRUENSOPAO-UHFFFAOYSA-N

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應用

铝镍合金可用于：
  • 将腈类、硝基和肟类化合物还原为一级胺。
  • 将羰基化合物转化为烃类物质。
  • 作为还原剂将Ar-X衍生物转化为Ar-H化合物。
  • 合成雷尼镍催化剂，用作烷化剂。
  • 通过碱浸法合成非自燃镍催化剂。
  • 合成合金的骨架镍催化剂。

法律資訊

Raney is a registered trademark of W.R. Grace & Co.-Conn.

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产品编号
说明
价格

訊號詞

Danger

危險分類

Carc. 2 - Flam. Sol. 1 - Skin Sens. 1 - Water-react 2

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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分析证书(COA)

Lot/Batch Number
STBL4833
STBL4241
STBL2362
STBL0821
STBK7565

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Highly selective hydrogenation of C?C double bond in unsaturated carbonyl compounds over NiC catalyst.
Mahata N, et al.
Chemical Engineering Journal, 188(4), 155-159 (2012)
An environmentally benign and catalytically efficient non-pyrophoric Ni catalyst for aqueous-phase reforming of ethylene glycol.
Zhu LJ, et al.
Green Chemistry, 10(12), 1323-1330 (2008)
Reinvestigating Raney nickel mediated selective alkylation of amines with alcohols via hydrogen autotransfer methodology.
Mehta A, et al.
Applied Catalysis A: General, 478(4), 241-251 (2014)
Nickel-aluminum alloy as a reducing agent.
Keefer LK and Lunn G
Chemical Reviews, 89(3), 459-502 (1989)
Steam reforming of ethanol over skeletal Ni-based catalysts: A temperature programmed desorption and kinetic study
Zhang C, et al.
AIChE Journal, 60(2), 635-644 (2014)
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商品

Self-Propagating Reactions Induced by Mechanical Alloying

Mechanical alloying is a “brute force” method of affecting alloying and chemical reactions. The mixture of reactant powders and several balls are placed in the milling jar of a high-energy ball mill, for example, a shaker mill or a planetary mill.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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