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质量水平
方案
96%
折射率
n20/D 1.465 (lit.)
沸点
88-91.5 °C (lit.)
密度
1.065 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
CC(S)=O
InChI
1S/C2H4OS/c1-2(3)4/h1H3,(H,3,4)
InChI key
DUYAAUVXQSMXQP-UHFFFAOYSA-N
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应用
硫代乙酸 (TAA) 可在新型亚磺酰基脲有机催化剂存在下,与硝基烯烃发生
- 对映体选择性加成,形成手性 1,2-氨基硫醇衍生物。该方法已成功地用于抗真菌药物硫康唑的合成。
- 双官能团胺硫脲催化不对称 Michael 加成反应,生成硫酯。
- 不对称 1,6-共轭加成反应 对位 -醌甲烷在手性磷酸催化剂存在下生成手性含硫二苯基甲烷型化合物。
- 甲基丙烯酰胺与手性反式-2,5-二取代吡咯烷助剂的共轭加成形成手性 β-巯基羧酸衍生物。
硫代乙酸是将巯基引入有机分子的试剂。
警示用语:
Danger
危险分类
Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Sens. 1
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
64.4 °F - closed cup
闪点(°C)
18 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
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