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Merck
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文件

P55708

Sigma-Aldrich

(R)-(+)-胡薄荷酮

85%, technical grade

别名:

(+)-蒲勒酮, (R)-(+)-长叶薄荷酮, (R)-2-异亚丙基-5-甲基环己酮, 长叶薄荷酮

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About This Item

经验公式（希尔记法）:
C10H16O
CAS号:
89-82-7
分子量:
152.23
Beilstein:
2040703
EC號碼:
201-943-2
MDL號碼:
MFCD00063000
分類程式碼代碼:
85151701
PubChem物質ID:
24898670
NACRES:
NA.22

等級

technical grade

品質等級

100

蒸汽壓力

138 mmHg ( 25 °C)

化驗

85%

光學活性

[α]20/D +22°, neat

折射率

n20/D 1.486 (lit.)

bp

224 °C (lit.)

密度

0.937 g/mL at 25 °C (lit.)

SMILES 字串

C[C@@H]1CC\C(=C(\C)C)C(=O)C1

InChI

1S/C10H16O/c1-7(2)9-5-4-8(3)6-10(9)11/h8H,4-6H2,1-3H3/t8-/m1/s1

InChI 密鑰

NZGWDASTMWDZIW-MRVPVSSYSA-N

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相关类别

一般說明

(R)-(+)-Pulegone, a monoterpene ketone found in essential oil of pennyroyal, can induce abortion.

應用

(R)-(+)-Pulegone may be used as a starting material to synthesize:
  • (2S,4R,6R,8S)-2,4,8-trimethyl-1,7-dioxaspiro[5.5]undecane, a spiroketal
  • (R)-(+)-citronellic acid, an intermediate to prepare leucine-d3
  • (+)-fawcettidine, a Lycopodium alkaloid

象形圖

Health hazardExclamation mark
GHS08,GHS07

訊號詞

Warning

危險聲明

H302,H351

危險分類

Acute Tox. 4 Oral - Carc. 2

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 1

閃點（°F）

179.6 °F - closed cup

閃點（°C）

82 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Synthesis of (2S, 4S)-and (2S, 4R)-[5,5,5-2H3] leucine from (R)-pulegone.
Hill RK, et al.
Canadian Journal of Chemistry, 72(1), 110-113 (1994)
Total Synthesis of (+)-Fawcettidine.
Kozak JA and Dake GR.
Angewandte Chemie (International Edition in English), 47(22), 4221-4223 (2008)
From (R)-(+)-pulegone to (2S,4R,6R,8S)-2,4,8-trimethyl-1,7-dioxaspiro[5.5]undecane-A unique spiroacetal from the insect Kingdom.
Tu YQ, et al.
Tetrahedron Asymmetry, 6(2), 397-400 (1995)
Metabolism of (R)-(+)-pulegone in F344 rats.
Chen LJ, et al.
Drug Metabolism and Disposition, 29(12), 1567-1577 (2001)
Chang-Qin Li et al.
Zhongguo Zhong yao za zhi = Zhongguo zhongyao zazhi = China journal of Chinese materia medica, 37(21), 3173-3175 (2013-02-13)
To study the validity of Schizonepeta tenuifalia pieces. The change principle for the contents of essential oil and pulegone was determined by the way of classical constant temperature acceleration experiment, and the reacting speed at 20 degrees C was calculated
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