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Merck

P13800

Sigma-Aldrich

1-苯基乙醇

98%

别名:

(±)-1-苯乙醇, (±)-α-甲基苄醇, 甲基苯基甲醇, 苏合香醇, 苯乙烯醇

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About This Item

线性分子式:
C6H5CH(OH)CH3
CAS号:
分子量:
122.16
Beilstein:
1905149
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
价格与库存信息目前不能提供

蒸汽密度

4.21 (vs air)

蒸汽压

0.1 mmHg ( 20 °C)

方案

98%

折射率

n20/D 1.527 (lit.)

沸点

204 °C/745 mmHg (lit.)

mp

19-20 °C (lit.)

密度

1.012 g/mL at 25 °C (lit.)

SMILES字符串

CC(O)c1ccccc1

InChI

1S/C8H10O/c1-7(9)8-5-3-2-4-6-8/h2-7,9H,1H3

InChI key

WAPNOHKVXSQRPX-UHFFFAOYSA-N

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应用

  • 1-苯基乙醇可用于酸催化的 Ritter 反应,以合成各种 N-苄基乙酰胺。[1][2]
  • 它是通过钯催化的羟基取向环化合成 [60] 富勒烯稠合的异色满衍生物的关键前体之一。[3]
  • 它用于弗里德兰德喹啉合成反应,其中 1-苯基乙醇与 2-氨基苄醇衍生物反应生成相应的醌。[4]
  • 它也可用于区域选择性、铱催化的嘧啶多组分合成。[5]

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Oral - Eye Irrit. 2

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

闪点(°F)

187.9 °F - Pensky-Martens closed cup

闪点(°C)

86.6 °C - Pensky-Martens closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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其他客户在看

Transition-metal-free indirect friedlander synthesis of quinolines from alcohols.
Martinez R, et al.
The Journal of Organic Chemistry, 73(24), 9778-9780 (2008)
FeCl3-catalyzed Ritter reaction. Synthesis of amides.
Anxionnat B, et al.
Tetrahedron Letters, 50(26), 3470-3473 (2009)
Synthesis of [60] fullerene-fused tetrahydrobenzooxepine and isochroman derivatives via hydroxyl-directed C?H activation/C?O cyclization.
Zhai W Q, et al.
Organic Letters, 16(6), 1638-1641 (2014)
A sustainable multicomponent pyrimidine synthesis.
Deibl N, et al.
Journal of the American Chemical Society, 137(40), 12804-12807 (2015)
The Ritter reaction under truly catalytic Br?nsted acid conditions.
Sanz R, et al.
European Journal of Organic Chemistry, 2007(28), 4642-4645 (2007)

Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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