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M72803

Sigma-Aldrich

2-甲基哌啶

98%

别名:

α-甲基哌啶, 2-哌可啉, NSC 31047, NSC 462

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About This Item

经验公式（希尔记法）:
C6H13N
CAS号:
109-05-7
分子量:
99.17
Beilstein:
79804
EC號碼:
203-642-1
MDL號碼:
MFCD00005982
分類程式碼代碼:
12352100
PubChem物質ID:
24897152
NACRES:
NA.22

化驗

98%

形狀

liquid

折射率

n20/D 1.445 (lit.)

bp

118-119 °C/753 mmHg (lit.)

密度

0.844 g/mL at 25 °C (lit.)

SMILES 字串

CC1CCCCN1

InChI

1S/C6H13N/c1-6-4-2-3-5-7-6/h6-7H,2-5H2,1H3

InChI 密鑰

NNWUEBIEOFQMSS-UHFFFAOYSA-N

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相关类别

應用

通过定向过渡金属催化的sp3 C-H活化进行哌啶C-2芳基化的反应物

用于合成以下物质的反应物：
  • 通过两步[5+2]成环反应合成氮杂环庚
  • 2-氨基苯并恶唑
  • 不对称取代脲
  • 促肾上腺皮质激素释放因子受体1型拮抗剂
  • 具有抗肿瘤活性的吉非替尼类似物

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

50.0 °F - closed cup

閃點（°C）

10 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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硫代醋酸 96%

Sigma-Aldrich

T30805

硫代醋酸

哌啶 ReagentPlus®, 99%

Sigma-Aldrich

104094

哌啶

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A novel series of [6-chloro-2-trifluoromethyl-7-aryl-7H-imidazo[1,2-a]imidazol-3-ylmethyl]-dialkylamines was discovered as potent CRF(1)R antagonists. The optimization of binding affinity in the series by the parallel reaction approach is discussed herein.
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Bioorganic & medicinal chemistry, 18(11), 3812-3822 (2010-05-15)
There is an urgent need to design and develop new and more potent EGFR inhibitors with improved anti-tumor activity. Here we describe the design and synthesis of two series of 4-benzothienyl amino quinazolines as new analogues of the EGFR inhibitor
Christopher L Cioffi et al.
The Journal of organic chemistry, 75(22), 7942-7945 (2010-10-27)
The synthesis of 2-aminobenzoxazoles can be readily achieved by two versatile, one-pot procedures utilizing commercially available tetramethyl orthocarbonate or 1,1-dichlorodiphenoxymethane, an amine, and an optionally substituted 2-aminophenol. The reactions were conducted under mild conditions and provided 2-aminobenzoxazoles in modest to
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Chemical communications (Cambridge, England), 46(19), 3351-3353 (2010-05-06)
A surprisingly efficient synthesis of azepan-4-ones via a two-step [5 + 2] annulation is developed. This reaction involves a key gold catalysis and shows generally high regioselectivities and good to excellent diastereoselectivities.
C-2 arylation of piperidines through directed transition-metal-catalyzed sp3 C-H activation.
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Chemistry (Weinheim an der Bergstrasse, Germany), 16(44), 13063-13067 (2010-10-29)
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