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Merck

D8801

Sigma-Aldrich

2,6-二乙酰基吡啶

98%

别名:

1,1′-(2,6-吡啶二基)二乙酮, 1-(6-乙酰吡啶-2-基)乙酮

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About This Item

经验公式(希尔记法):
C9H9NO2
CAS号:
分子量:
163.17
Beilstein:
118286
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

98%

mp

79-82 °C (lit.)

SMILES 字串

CC(=O)c1cccc(n1)C(C)=O

InChI

1S/C9H9NO2/c1-6(11)8-4-3-5-9(10-8)7(2)12/h3-5H,1-2H3

InChI 密鑰

BEZVGIHGZPLGBL-UHFFFAOYSA-N

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應用

2,6-二乙酰基吡啶可用作合成以下物质的起始原料:
  • 铁和钴双(亚氨基)吡啶基配合物,乙烯低聚的催化剂。ios硫代氨基脲衍生物可作为抗分枝杆菌性结核病的药物。
  • 大环五齿氮硫供体配体与1,2-二(o-氨基苯硫基)乙烷[1 + 1]缩合。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Thiosemicarbazones, semicarbazones, dithiocarbazates and hydrazide/hydrazones: Anti-Mycobacterium tuberculosis activity and cytotoxicity.
Pavan FR, et al.
European Journal of Medicinal Chemistry, 45(5), 1898-1905 (2010)
Oligomerisation of Ethylene by Bis (imino) pyridyliron and-cobalt Complexes.
Britovsek GJP, et al.
Chemistry?A European Journal , 6(12), 2221-2231 (2000)
Chromium (III), manganese (II), iron (III), cobalt (II), nickel (II) and copper (II) complexes with a pentadentate, 15-membered new macrocyclic ligand.
Chandra S and Gupta K
Transition Metal Chemistry, 27(2), 196-199 (2002)
Manja Kubeil et al.
ChemistryOpen, 8(5), 637-642 (2019-05-30)
A photoactivatable ruthenium(II) carbonyl complex mer,cis-[Ru(II)Cl(BisQ)(CO)2]PF62 was prepared using a tridentate bisquinoline ligand (BisQ=(2,6-diquinolin-2-yl)pyridin). Compound 2 was thoroughly characterized by standard analytical methods and single crystal X-ray diffraction. The crystal structure of the complex cation reveals a distorted octahedral geometry.
Ali Sayqal et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 242, 118711-118711 (2020-08-02)
Herein, the presented manuscript provides for an extensive spectrofluorimetric method for micro determination of silver ion. This established method based on the use of the three synthesized 2,6-disubstituted pyridine derivatives (R1, R2 and R3) through exploiting their high fluorescence emission

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