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C95501

Sigma-Aldrich

三聚氯氰

99%

别名:

2,4,6-三氯-1,3,5-三嗪

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About This Item

经验公式（希尔记法）:
C3Cl3N3
CAS号:
108-77-0
分子量:
184.41
Beilstein:
124246
EC 号:
203-614-9
MDL编号:
MFCD00006046
UNSPSC代码:
12352101
PubChem化学物质编号:
24893171
NACRES:
NA.22

蒸汽密度

6.36 (vs air)

质量水平

200

蒸汽压

0.8 mmHg ( 62.2 °C)

方案

99%

表单

powder

沸点

190 °C (lit.)

mp

145-147 °C (lit.)

储存温度

2-8°C

SMILES字符串

Clc1nc(Cl)nc(Cl)n1

InChI

1S/C3Cl3N3/c4-1-7-2(5)9-3(6)8-1

InChI key

MGNCLNQXLYJVJD-UHFFFAOYSA-N

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应用

三聚氰胺可用作以下应用的试剂：   
  • 从羧酸和叠氮化钠制备酰基叠氮。       
  • 将羧酸、N-Boc、 N-Cbz和N-Fmoc氨基酸转化为相应的醇。      
  • 通过替代Swern氧化反应将醇类转化为相应的羰基化合物。


此外，在ZnCl2存在的情况下，还可作为酮肟转化成酰胺的Beckmann重排催化剂。
用于醇转化为氯化物的试剂，用于微生物和酶的固化。

象形图

Skull and crossbonesCorrosion
GHS06,GHS05

警示用语：

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1A - STOT SE 3

靶器官

Respiratory system

补充剂危害

EUH014

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 1

闪点(°F)

>392.0 °F - closed cup

闪点(°C)

> 200 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCL4782
BCCJ3177
BCCK7153
BCCJ7568
BCCG7996

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J. Mol. Catal., 80, 269-269 (1993)
A mild and efficient alternative to the classical Swern oxidation.
L De Luca et al.
The Journal of organic chemistry, 66(23), 7907-7909 (2001-11-10)
Synthesis of acyl azides from carboxylic acids using cyanuric chloride
Bandgar BP and Pandit SS
Tetrahedron Letters, 43(18), 3413-3414 (2002)
Mild reduction of carboxylic acids to alcohols using cyanuric chloride and sodium borohydride
Falorni M, et al.
Tetrahedron Letters, 40(23), 4395-4396 (1999)
Sanjay K Singh et al.
Frontiers in immunology, 11, 1812-1812 (2020-09-10)
C-reactive protein (CRP), a component of the innate immune system, is an antipneumococcal plasma protein. Human CRP has been shown to protect mice against infection with lethal doses of Streptococcus pneumoniae by decreasing bacteremia. in vitro, CRP binds to phosphocholine-containing
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