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C22369

Sigma-Aldrich

2-氯丙烯腈

98%

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About This Item

线性分子式:
CH2=CClCN
CAS号:
920-37-6
分子量:
87.51
Beilstein:
773744
MDL號碼:
MFCD00001858
分類程式碼代碼:
12352100
PubChem物質ID:
24892478
NACRES:
NA.22

品質等級

200

化驗

98%

形狀

liquid

折射率

n20/D 1.429 (lit.)

bp

88-89 °C (lit.)

mp

−65 °C (lit.)

密度

1.096 g/mL at 25 °C (lit.)

SMILES 字串

ClC(=C)C#N

InChI

1S/C3H2ClN/c1-3(4)2-5/h1H2

InChI 密鑰

OYUNTGBISCIYPW-UHFFFAOYSA-N

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應用

环加成反应中的通用试剂。

訊號詞

Danger

危險分類

Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 3 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Resp. Sens. 1 - Skin Corr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

42.8 °F - closed cup

閃點（°C）

6 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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异丙基氯化镁 溶液 2.0 M in THF

Sigma-Aldrich

230111

异丙基氯化镁 溶液

Journal of the Chemical Society. Chemical Communications, 814-814 (1993)
The Journal of Organic Chemistry, 58, 5200-5200 (1993)
A G Craan et al.
Toxicology, 56(1), 47-61 (1989-05-31)
The nephrotoxicity of glutathione (GSH) pathway metabolites derived from toluene (TOL), styrene (STYR), bromobenzene (BB), acrylonitrile (ACLN) and 2-chloroacrylonitrile (CACLN) were compared with that of dichlorovinylcysteine (DCVC), using renal brush border and basal-lateral uptake parameters as indices. Cysteine conjugates and
Yi Wang et al.
Journal of the American Chemical Society, 128(12), 3928-3930 (2006-03-23)
Catalytic tandem asymmetric reactions constitute a powerful strategy for the asymmetric construction of nonadjacent stereocenters in acyclic molecules directly from achiral precursors. In this Communication, we report a highly enantioselective and diastereoselective addition of trisubstituted carbon donors to 2-chloroacrylonitrile catalyzed
Asymmetric conjugate addition of oxindoles to 2-chloroacrylonitrile: a highly effective organocatalytic strategy for simultaneous construction of 1,3-nonadjacent stereocenters leading to chiral pyrroloindolines.
Xin Li et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(48), 14290-14294 (2010-12-01)
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