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Merck
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文件

ALD00004

Sigma-Aldrich

Li-Yu t-Butyl Quinoline

95%

别名:

3,4-Dihydro-7-tert-butyl-2,5-dimethyl-2H-pyrano[2,3-b]quinoline

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About This Item

经验公式（希尔记法）:
C18H23NO
分子量:
269.38
MDL號碼:
MFCD28016344
分類程式碼代碼:
12352005
PubChem物質ID:
329772510
NACRES:
NA.22

化驗

95%

形狀

solid

反應適用性

reaction type: C-C Bond Formation
reagent type: catalyst
reagent type: ligand
reaction type: C-H Activation

mp

202-207 °C

SMILES 字串

CC1=C2C(OC(C)CC2)=NC3=C1C=C(C(C)(C)C)C=C3

InChI

1S/C18H23NO/c1-11-6-8-14-12(2)15-10-13(18(3,4)5)7-9-16(15)19-17(14)20-11/h7,9-11H,6,8H2,1-5H3

InChI 密鑰

HGKGTNXPFXRVQB-UHFFFAOYSA-N

相关类别

應用

Ligand is optimal for gamma C-H functionalization of aliphatic acids through Pd-catalyzed C-H activation. The Yu group has demonstrated a variety of transformations, such as olefination, carbonylation, and arylation.

其他說明

Ligand-Enabled g-C–H Olefination and Carbonylation: Construction of b-Quaternary Carbon Centers

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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相关内容

Yu Group – Professor Product Portal

The Yu program centers around the discovery of catalytic carbon–carbon and carbon–heteroatom bond forming reactions based on C–H activation. Target transformations are selected to enable 1) the use of simple and abundant starting materials such as aliphatic acids, amines and alcohols, and 2) disconnections that drastically shorten the synthesis of a drug molecule or a major class of biologically active compounds.

我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

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