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Merck

923230

Sigma-Aldrich

2,4-Spiro-OMeTAD

greener alternative

≥98.5% (HPLC)

别名:

2,4-Spiro-OMeTAD, N2,N2′,N7,N7′-Tetrakis(2,4-dimethoxyphenyl)-N2,N2′,N7,N7′-tetraphenyl-9,9′-spirobi[fluorene]-2,2′,7,7′-tetraamine

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About This Item

经验公式(希尔记法):
C81H68N4O8
分子量:
1225.43
分類程式碼代碼:
41116107
NACRES:
NA.23

描述

Band gap 3.2 eV

品質等級

化驗

≥98.5% (HPLC)

環保替代產品特色

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

溶解度

chloroform: soluble

軌道能量

HOMO -5.24 eV 
LUMO -2.08 eV 

環保替代類別

SMILES 字串

COC1=CC(OC)=CC=C1N(C2=CC=CC=C2)C3=CC=C4C(C5(C(C=C(N(C6=C(OC)C=C(OC)C=C6)C7=CC=CC=C7)C=C8)=C8C9=C5C=C(N(C%10=CC=C(OC)C=C%10OC)C%11=CC=CC=C%11)C=C9)C%12=C4C=CC(N(C%13=C(OC)C=C(OC)C=C%13)C%14=CC=CC=C%14)=C%12)=C3

InChI 密鑰

WOFKCKQGJWGUFS-UHFFFAOYSA-N

一般說明

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product belongs to enabling category of greener alternatives, and has been enhanced for energy efficiency. Click here for more information.

應用

High-mobility organic semiconductor hole transport material (HTM) for use in electron transport layer in sensors, OPV and OLED applications. Derivatives of spiro-OMeTAD have been widely studied because of their outstanding performance. It was demonstrated that 2,4-spiro-OMeTAD as HTM in photovoltaic cells shows excelent stability and power conversion efficiency in perovskite solar cells. Zhang et al reported a power conversion efficiency of 17.2% and solar cell filling factor of 70.1% when using 2,4-spiro-OMeTAD.
Spiro-MeOTAD can be used as a hole transport material in perovskite solar cells and solid-state dye-sensitized solar cells (DSSCs) as it helps to efficiently extract and transport positive charges (holes) from the perovskite layer to the electrode, improving the overall device performance and stability. It can be used as a hole injection and transport material in OLEDs, especially in small molecule-based and solution-processed OLEDs.

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Structure-performance relationship on the asymmetric methoxy substituents of spiro-OMeTAD for perovskite solar cells.
Zhang M D, et al.
Solar Energy Mat. and Solar Cells, 176, 318-323 (2018)

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