908711

Ni(IMes)(di-t-butyl fumarate)₂

• 别名: Montgomery Ni catalyst
• 经验公式（希尔记法）: C₄₅H₆₄N₂NiO₈
• CAS号: 2230140-59-5
• 分子量: 819.69
• MDL编号: MFCD31747046
• UNSPSC代码: 12352103
• NACRES: NA.22

属性

• 表单: powder
• 反应适用性: reagent type: catalyst; reaction type: Cross Couplings
• SMILES字符串: [Ni].N2(CN(C=C2)c3c(cc(cc3C)C)C)c1c(cc(cc1C)C)C.O(C(C)(C)C)C(=O)\C=C\C(=O)OC(C)(C)C.O(C(C)(C)C)C(=O)\C=C\C(=O)OC(C)(C)C
• InChI key: NAUZISBIAJSKIT-RKDKPBPFSA-N

说明

应用

Ni(IMes)(di-t-butyl fumarate)₂ is an NHC-Ni(0) precatalyst developed in the Montgomery lab used for a variety of synthetic transformations including reductive couplings of aldehydes and alkynes and N-arylation of amines.

其他说明

Stable, Well-Defined Nickel(0) Catalysts for Catalytic C–C and C–N Bond Formation

安全信息

• 储存分类代码: 11 - Combustible Solids
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable