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Merck

901695

Sigma-Aldrich

四氟硼酸锂

≥98%, acid <200 ppm, anhydrous

别名:

氟硼酸锂

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About This Item

线性分子式:
LiBF4
CAS号:
分子量:
93.75
MDL编号:
UNSPSC代码:
12352302
NACRES:
NA.23
方案:
≥98%
等级:
anhydrous
表单:
powder

等级

anhydrous

方案

≥98%

表单

powder

mp

293-300 °C (dec.) (lit.)

应用

battery manufacturing

SMILES字符串

[Li+].F[B-](F)(F)F

InChI

1S/BF4.Li/c2-1(3,4)5;/q-1;+1

InChI key

UFXJWFBILHTTET-UHFFFAOYSA-N

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一般描述

Lithium tetrafluoroborate (LiBF4), a lithium salt, exhibits high conductivity, low electrical charge transfer, moisture resistance, and good cyclic properties. It is suitable for a low-temperature electrolytic system. Its performance is comparable to the widely used LiPF6 system.

应用

Lithium tetrafluoroborate (LiBF4) finds application as electrolyte material in lithium ion batteries (LIBs). However, the presence of trace amount of water in LiBF4 causes its hydrolysis which leads to HF generation and destruction of the battery electrodes. Our LiBF4 contains < 100 ppm of water and is well suited for applications in LIBs.

注意

  • These electrolyte solutions have extremely low water content; Please handle under inert and moisture free environment (glove box).
  • Keep away from heat, sparks and flame. Avoid moisture, strong acid, strong alkalis, and oxidizing agents. Avoid skin and eye contact from product. Highly toxic and corrosive gases (HF) are generated by reaction with moisture os use only under inert gas atmosphere.
  • Please handle under inert and moisture free environment.

Storage:
Keep containers away from heat, humidity, direct sunlight and ignition source. Keep containers tightly closed in a cool dry and well-ventilated place. Do not store with strong oxidizing agents.

法律信息

Product of Ube Industries Ltd.

警示用语:

Danger

危险声明

危险分类

Acute Tox. 4 Oral - Eye Dam. 1 - Muta. 2 - Skin Corr. 1B

储存分类代码

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Doi T, et al.
Journal of the Electrochemical Society, 163, A2211-A2215 (2016)
Conductivity and electrical properties of chitosan-methylcellulose blend biopolymer electrolyte incorporated with lithium tetrafluoroborate
Salman YAK, et al.
International Journal of Electrochemical Science, 13, 3185-3199 (2018)
Investigation of the synergetic effects of LiBF 4 and LiODFB as wide-temperature electrolyte salts in lithium-ion batteries
Zhang Li
Ionics, 24(10), 2995-3004 (2018)
Zuo X, et al.
Journal of the Electrochemical Society, 160, A1199-A1204 (2013)
Vanchiappan Aravindan et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(51), 14326-14346 (2011-11-25)
This paper presents an overview of the various types of lithium salts used to conduct Li(+) ions in electrolyte solutions for lithium rechargeable batteries. More emphasis is paid towards lithium salts and their ionic conductivity in conventional solutions, solid-electrolyte interface

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