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768154

2-(二-1-金刚烷基膦基)-3,6-二甲氧基-2',4',6'-三异丙基-1,1' - 联苯

Name: 2-(二-1-金刚烷基膦基)-3,6-二甲氧基-2',4',6'-三异丙基-1,1' - 联苯
Brand: ALDRICH

95%

别名:

2-(二-1-金刚烷基膦)-3,6-二甲氧基-2',4',6'-三异丙基-1,1'-联苯

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About This Item

经验公式（希尔记法）:

C₄₃H₆₁O₂P

CAS号:

1160861-59-5

分子量:

640.92

分類程式碼代碼:

12352112

PubChem物質ID:

329767360

NACRES:

NA.22

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2-{双[3,5-双(三氟甲基)苯基]膦基}-3,6-二甲氧基-2′,4′,6′-三异丙基-1,1′-联苯

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化驗

95%

形狀

solid

反應適用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

mp

231-235 °C

官能基

phosphine

SMILES 字串

COc1ccc(OC)c(c1P(C23CC4CC(CC(C4)C2)C3)C56CC7CC(CC(C7)C5)C6)-c8c(cc(cc8C(C)C)C(C)C)C(C)C

InChI

1S/C43H61O2P/c1-25(2)34-17-35(26(3)4)39(36(18-34)27(5)6)40-37(44-7)9-10-38(45-8)41(40)46(42-19-28-11-29(20-42)13-30(12-28)21-42)43-22-31-14-32(23-43)16-33(15-31)24-43/h9-10,17-18,25-33H,11-16,19-24H2,1-8H3

InChI 密鑰

NMGHOZQCYNKWBG-UHFFFAOYSA-N

一般說明

AdBrettPhos 是一种膦基配体，用于氨的直接单芳基化，并抑制二芳基化。此外，它也是五元杂芳烃偶联的良好配体，并用于制备膦连接的钯复合物，以促进C-N偶联反应。

應用

AdBrettPhos 可用作合成[（L·Pd）_n ·（1,5-环辛二烯）]预催化剂的有效配体，该预催化剂可用于芳基三氟甲磺酸酯的钯催化氟化。

918008

GPhos, ≥95%

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

分析证书(COA)

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Buchwald and non-Buchwald catalysts and ligands for pharma or industrial chemistry applications

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Buchwald and non-Buchwald catalysts and ligands for pharma or industrial chemistry applications

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2-(二-1-金刚烷基膦基)-3,6-二甲氧基-2',4',6'-三异丙基-1,1' - 联苯