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Merck

518352

Sigma-Aldrich

2-羟甲基-3,4-二氢吡喃,聚合物键合型

extent of labeling: ~0.7 mmol/g loading, 1 % cross-linked

别名:

DHP 树脂, Ellmans DHP 树脂

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About This Item

MDL號碼:
分類程式碼代碼:
12352202
PubChem物質ID:
NACRES:
NA.22

交聯

1 % cross-linked

反應適用性

reaction type: Fmoc solid-phase peptide synthesis
reactivity: alcohol reactive

標籤範圍

~0.7 mmol/g loading

SMILES 字串

C=Cc1ccccc1.C=Cc2ccc(C=C)cc2.C3CC(COCc4ccccc4)OC=C3

相关类别

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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相关内容

The Ellman group has participated in the development of a variety of C-H functionalization methods. An electron rich phosphine ligand has proven to be very useful for a variety of Rh(I)-catalyzed C-C bond forming reactions applicable to heterocycle synthesis as exemplified in the recent Science paper “Proton Donor Acidity Controls Selectivity in Nonaromatic Nitrogen Heterocycle Synthesis.” Another useful ligand developed for the highly functional group compatible direct arylation of nitrogen heterocycles is described in a 2008 J. Am. Chem. Soc. paper “Rh(I)-Catalyzed Arylation of Heterocycles via C-H Bond Activation: Expanded Scope through Mechanistic Insight.” The Ellman group also developed the chiral amine reagent tert-Butanesulfinamide, which is extensively used in academics and industry for the asymmetric synthesis of amines. A comprehensive survey of tert-Butanesulfinamide methods and applications up through 2009 is provided in the 2010 Chemical Reviews article, “Synthesis and Applications of tert-Butanesulfinamide.”

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