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Merck

495492

Sigma-Aldrich

叔丁基二甲基(2-丙炔氧基)硅烷

97%

别名:

(1,1-Dimethylethyl)dimethyl(2-propyn-1-yloxy)silane, 1-(tert-Butyldimethylsilyloxy)-2-propyne, 3-(Dimethyl-tert-butylsiloxy)propyne, 3-(tert-Butyldimethylsilyloxy)-1-propyne, 3-(tert-Butyldimethylsilyloxy)propyne, 3-tert-Butyldimethylsiloxy-1-propyne, Dimethyl(2-Propynyloxy)(tert-butyl)silane

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About This Item

线性分子式:
(CH3)3CSi(CH3)2OCH2C≡CH
CAS号:
分子量:
170.32
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

97%

折射率

n20/D 1.429 (lit.)

bp

40 °C/8 mmHg (lit.)

密度

0.84 g/mL at 25 °C (lit.)

SMILES 字串

CC(C)(C)[Si](C)(C)OCC#C

InChI

1S/C9H18OSi/c1-7-8-10-11(5,6)9(2,3)4/h1H,8H2,2-6H3

InChI 密鑰

ZYDKYFIXEYSNPO-UHFFFAOYSA-N

一般說明

tert-Butyldimethyl(2-propynyloxy)silane is an aliphatic terminal alkyne.

應用

tert-Butyldimethyl(2-propynyloxy)silane may be used in the synthesis of (R)-2,3-pentadecadien-1-ol and (S)-ethyl 5-(tert-butyldimethylsilyloxy)-2-hydroxy-2-phenylpent-3-ynoate.

象形圖

Flame

訊號詞

Warning

危險聲明

防範說明

危險分類

Flam. Liq. 3

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

101.8 °F

閃點(°C)

38.8 °C

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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An Enantioselective Synthesis of (R)-5,6-Octadecadienoic Acid.
Yu Q and Ma S.
European Journal of Organic Chemistry, 2015(7), 1596-1601 (2015)
Enantiocontrolled Synthesis of Tertiary α-Hydroxy-α-ynyl Esters by Dimethylzinc-Mediated Addition of Alkynes to α-Keto Esters.
Infante R, et al.
Advanced Synthesis & Catalysis, 354(14-15), 2797-2804 (2012)

商品

Alkynes' versatility enables reactions like addition, metathesis, hydroboration, cleavage, coupling, and cycloadditions in synthetic chemistry.

Alkynes' versatility enables reactions like addition, metathesis, hydroboration, cleavage, coupling, and cycloadditions in synthetic chemistry.

Alkynes' versatility enables reactions like addition, metathesis, hydroboration, cleavage, coupling, and cycloadditions in synthetic chemistry.

Alkynes' versatility enables reactions like addition, metathesis, hydroboration, cleavage, coupling, and cycloadditions in synthetic chemistry.

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