483656

双(环戊二烯基)二甲基锆(IV)

97%

• 别名: Dimethyldicyclopentadienylzirconium, Dimethylzirconocene
• 线性分子式: (C₅H₅)₂Zr(CH₃)₂
• CAS号: 12636-72-5
• 分子量: 251.48
• MDL號碼: MFCD01073786
• 分類程式碼代碼: 12161600
• PubChem物質ID: 24871906
• NACRES: NA.22

属性

• 品質等級: 100
• 化驗: 97%
• 反應適用性: core: zirconium; reagent type: catalyst; reaction type: Olefin Metathesis
• mp: 170 °C (dec.) (lit.)
• SMILES 字串: C[Zr]C.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
• InChI: 1S/2C5H5.2CH3.Zr/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H3;
• InChI 密鑰: BRHODLBZJKAKRN-UHFFFAOYSA-N

说明

應用

Catalyst for:

• Cationic ring-opening polymerization reactions
• Markovnikov-selective intermolecular hydrothiolation of terminal alkynes
• Ziegler-Natta polymerizations of alkenes
• Methylalumination of heterosubstituted arylethynes

• Precatalyst for intramolecular hydroamination/cyclisation of aminoallenes

安全信息

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319
• 防範說明: P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 個人防護裝備: Eyeshields, Gloves, type N95 (US)