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Merck

462292

Sigma-Aldrich

N-苄基乙二胺

97%

别名:

2-苄基氨基乙胺

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About This Item

线性分子式:
C6H5CH2NHCH2CH2NH2
CAS号:
分子量:
150.22
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

方案

97%

折射率

n20/D 1.54 (lit.)

沸点

162 °C/20 mmHg (lit.)

密度

1 g/mL at 25 °C (lit.)

官能团

amine
phenyl

SMILES字符串

NCCNCc1ccccc1

InChI

1S/C9H14N2/c10-6-7-11-8-9-4-2-1-3-5-9/h1-5,11H,6-8,10H2

InChI key

ACYBVNYNIZTUIL-UHFFFAOYSA-N

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一般描述

N-Benzylethylenediamine participates in the one-pot synthesis of N,N,N′-trisubstituted guanidines. It undergoes condensation with dibenzoylmethane (1,3-diphenyl-1,3-propanedione) in stoichiometric ratio 1:1 to afford the corresponding Schiff monobase.

应用

N-Benzylethylenediamine may be used for the synthesis of N-benzyl-N,N′,N′-tris(tert-butyloxycarbonylmethyl)ethylenediamine and 3-benzyl-2-(phenyl-2-sulfonate)-2-imidazoline tetraheptylammonium salt.

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Skin Corr. 1B

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

203.0 °F - closed cup

闪点(°C)

95 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A new method for the synthesis of tri-tert-butyl diethylenetriaminepentaacetic acid and its derivatives.
Achilefu S, et al.
The Journal of Organic Chemistry, 65(5), 1562-1565 (2000)
Anthony Weatherwax et al.
Organic letters, 7(16), 3461-3463 (2005-07-29)
Trans-disubstituted beta-lactams show increasing utility and prominence in numerous pharmaceutical applications, making their asymmetric synthesis an attractive goal for chemists. We introduce an anionic, nucleophilic catalyst system that provides an efficient, diastereoselective route to trans-disubstituted beta-lactams, a complement to our
Nickel (II) Complexes of Dibenzoylmethane and N-benzylethylenediamine, and Their Schiff Monobase.
Gutierrez JA, et al.
Journal of Coordination Chemistry, 28(3-4), 305-312 (1993)
Application of a-chloroaldoxime O-methanesulfonates to one-pot synthesis of N, N', N?-substituted guanidines via Tiemann rearrangement.
Yamamoto Y, et al.
Tetrahedron Letters, 50(42), 5813-5815 (2009)

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