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About This Item
经验公式（希尔记法）:
C14H16NP
CAS号:
分子量:
229.26
Beilstein:
644931
MDL號碼:
分類程式碼代碼:
12352116
PubChem物質ID:
NACRES:
NA.22
推荐产品
化驗
≥95.0% (GC)
形狀
liquid
反應適用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
官能基
phosphine
SMILES 字串
NCCP(c1ccccc1)c2ccccc2
InChI
1S/C14H16NP/c15-11-12-16(13-7-3-1-4-8-13)14-9-5-2-6-10-14/h1-10H,11-12,15H2
InChI 密鑰
RXEPBCWNHKZECN-UHFFFAOYSA-N
一般說明
2-(二苯基膦基)乙胺是一种双齿结构的膦配体，磷原子提供两对孤对电子供金属离子配位。可用作反应剂，合成酰胺化合物选择性氢化反应的活性催化剂。它也被用作合成其他膦配体的前体。
應用
2-(二苯基膦基)乙胺可用作镍催化体系中的双齿配体，用于炔烃经还原[2+2]环加成合成环丁烯的反应。
訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1 - Skin Corr. 1B
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Nickel-catalyzed reductive [2+ 2] cycloaddition of alkynes
Canellas S, et al.
Journal of the American Chemical Society, 140(50), 17349-17355 (2018)
A highly active catalyst for the hydrogenation of amides to alcohols and amines
Angewandte Chemie (International Edition in English), 50(44), 10377-10380 (2011)
Youngwon Kim et al.
Journal of inorganic biochemistry, 205, 111015-111015 (2020-02-08)
A pyrrolyl-iminophosphine (PNNH) which would act as a potential terdentate ligand has been prepared by Schiff base reaction. Complexes [M(PNN)X] (M = Ni; X = Cl (1), Pd; X = Cl (2), Br (3), I (4), M = Pt; X = Cl (5)) were prepared. The title complexes were characterized
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