推荐产品
反應適用性
reaction type: Grignard Reaction
濃度
0.5 M in THF
密度
0.952 g/mL at 25 °C
SMILES 字串
C\C(C)=C\[Mg]Br
InChI
1S/C4H7.BrH.Mg/c1-4(2)3;;/h1H,2-3H3;1H;/q;;+1/p-1
InChI 密鑰
BKVIQODYSREJQH-UHFFFAOYSA-M
一般說明
2-甲基-1-丙烯基溴化镁是一种杂环有机化合物。它被用于化学合成中的格氏试剂。
應用
用于合成 (2S,3S)-3′-氟代异亮氨酸。
用于研究与芳基甲苯磺酸酯的钯催化偶联反应。
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
標靶器官
Respiratory system
安全危害
儲存類別代碼
4.3 - Hazardous materials which set free flammable gases upon contact with water
水污染物質分類（WGK）
WGK 3
閃點（°F）
5.0 °F - closed cup
閃點（°C）
-15 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
其他客户在看
Michael E Limmert et al.
The Journal of organic chemistry, 70(23), 9364-9370 (2005-11-05)
[Reaction: see text]. Aryl and alkenyl tosylates are easily prepared, inexpensive and, thus, attractive for transition-metal-catalyzed couplings, but their reactivity is low. We report examples of mild, palladium-catalyzed coupling of aryl, alkenyl, and alkyl Grignard reagents with aryl and alkenyl
Jean-Damien Charrier et al.
Organic & biomolecular chemistry, 2(5), 797-802 (2004-02-27)
The fluorinated amino acid, (2S,3S)-3'-fluoroisoleucine 3, has been synthesised by a route involving stereoselective cuprate or photochemical addition to the compound 4, derived in turn from (2S)-pyroglutamic acid. This provides a reporter group for the hydrophobic amino acid (2S)-isoleucine for
Enantioselective Oxy-Heck--Matsuda Arylations: Expeditious Synthesis of Dihydrobenzofuran Systems and Total Synthesis of the Neolignan (-)-Conocarpan
Silva AR, et al.
advanced synthesis and catalysis, 360(2), 346-365 (2018)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系技术服务部门