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Merck
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文件

398195

Sigma-Aldrich

锂 叔 -丁氧 溶液

1.0 M in THF

别名:

tert-Butoxylithium, Lithium 2-methylpropan-2-olate, Lithium t-butoxide, Lithium tert-butylate, Lithium salt of tert-Butyl alcohol

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About This Item

线性分子式:
(CH3)3COLi
CAS号:
1907-33-1
分子量:
80.05
Beilstein:
3620018
MDL號碼:
MFCD00050479
分類程式碼代碼:
12352300
PubChem物質ID:
24864726
NACRES:
NA.22

形狀

liquid

品質等級

100

濃度

1.0 M in THF

bp

67 °C

密度

0.888 g/mL at 25 °C

SMILES 字串

[Li+].CC(C)(C)[O-]

InChI

1S/C4H9O.Li/c1-4(2,3)5;/h1-3H3;/q-1;+1

InChI 密鑰

LZWQNOHZMQIFBX-UHFFFAOYSA-N

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應用

锂 叔 -丁氧基溶液在有机合成中一般作为强碱使用。
可用于：
  • 合成导电凝胶电解质用锂改性二氧化硅纳米颗粒。
  • 作为丙交酯开环聚合的催化剂。
  • 作为 LiV 3 O 8 纳米粒子火焰喷雾热解法合成的锂前驱体。

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Self-heat. 1 - Skin Corr. 1B - STOT SE 3

標靶器官

Central nervous system, Respiratory system

安全危害

EUH019

儲存類別代碼

4.2 - Pyrophoric and self-heating hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

-2.2 °F - closed cup

閃點（°C）

-19 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Dixon S, et al.
Tetrahedron Letters, 46(43), 7443-7446 (2005)
Electrochemistry of LiV3O8 nanoparticles made by flame spray pyrolysis.
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Gel electrolytes based on lithium modified silica nano-particles.
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