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Merck
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389439

Sigma-Aldrich

1-芘甲醇

98%

别名:

1-羟甲基芘, 1-（1-羟甲基）芘

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About This Item

经验公式（希尔记法）:
C17H12O
CAS号:
24463-15-8
分子量:
232.28
MDL编号:
MFCD00029252
UNSPSC代码:
12352100
PubChem化学物质编号:
24864285
NACRES:
NA.22

方案

98%

表单

solid

mp

123-126 °C (lit.)

官能团

hydroxyl

SMILES字符串

OCc1ccc2ccc3cccc4ccc1c2c34

InChI

1S/C17H12O/c18-10-14-7-6-13-5-4-11-2-1-3-12-8-9-15(14)17(13)16(11)12/h1-9,18H,10H2

InChI key

NGDMLQSGYUCLDC-UHFFFAOYSA-N

相关类别

应用

1-芘乙醇可用于：
  • 合成腺苷-5′ 的钳形苯桥接荧光选择性传感器-三磷酸盐 (ATP) 检测。
  • 作为合成芘端聚甲基丙烯酸缩水甘油酯聚合物的起始原料。
  • 作为合成芘核心星形聚合物的引发剂。
  • 合成医药和农药领域的重要中间体 1-芘甲醛。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBR0848
SHBL4554
SHBJ3992
SHBH0524V
SHBF4327V

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Encapsulation of functional moieties within branched star polymers: effect of chain length and solvent on site isolation.
Hecht S, et al.
Journal of the American Chemical Society, 123(1), 18-25 (2001)
H Glatt et al.
Carcinogenesis, 14(4), 599-602 (1993-04-01)
1-Hydroxymethylpyrene (HMP), a primary benzylic alcohol, and 4H-cyclopenta[def]chrysen-4-ol (OH-CPC), a secondary benzylic alcohol, were investigated for mutagenicity in Salmonella typhimurium (reversion of the his- strain TA98) in the presence of various xenobiotic-metabolizing systems. In the direct test, HMP was inactive
Walter Meinl et al.
Pharmacogenetics, 12(9), 677-689 (2002-12-05)
Various enzymatically formed sulfuric acid esters are chemically reactive and mutagenic. This metabolic activation pathway is not detected in standard in-vitro mutagenicity test systems. We describe the construction of Salmonella typhimurium TA1538-derived strains expressing alloenzymes *1, *2, *3, *5, *6
H Glatt et al.
Chemico-biological interactions, 109(1-3), 195-219 (1998-05-05)
Sulfation is a common final step in the biotransformation of xenobiotics and is traditionally associated with inactivation. However, the sulfate group is electron-withdrawing and may be cleaved off heterolytically in some molecules leading to electrophilic cations which may form adducts
Y J Surh et al.
Carcinogenesis, 11(9), 1451-1460 (1990-09-01)
Our previous studies on 7-hydroxymethyl-12-methylbenz[a]anthracene and 6-hydroxymethylbenzo[a]pyrene showed that cytosolic sulfotransferase activity plays a major role in the formation of hepatic benzylic DNA and RNA adducts by these carcinogens in rats. In the present study, we found similar sulfotransferase activity
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