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385638

Sigma-Aldrich

二甲基吡啶胺

97%

别名:

双(2-吡啶甲基)胺

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About This Item

经验公式（希尔记法）:
C12H13N3
CAS号:
1539-42-0
分子量:
199.25
EC 号:
216-266-8
MDL编号:
MFCD00129044
UNSPSC代码:
12352100
PubChem化学物质编号:
24864040
NACRES:
NA.22
价格与库存信息目前不能提供

质量水平

100

方案

97%

折射率

n20/D 1.578 (lit.)

沸点

139-141 °C/1 mmHg (lit.)

溶解性

water: soluble (partially miscible)(lit.)

密度

1.107 g/mL at 25 °C (lit.)

官能团

amine

SMILES字符串

C(NCc1ccccn1)c2ccccn2

InChI

1S/C12H13N3/c1-3-7-14-11(5-1)9-13-10-12-6-2-4-8-15-12/h1-8,13H,9-10H2

InChI key

KXZQYLBVMZGIKC-UHFFFAOYSA-N

相关类别

一般描述

二-(2-甲基吡啶)胺(DPA)，2个甲基吡啶取代的二级胺，因具有3个氮原子供体而用作三齿配体。常用于配位化学，与铜(Cu)和镉(Cd)等各种金属离子合成二元、三元和双核配合物。 [1]

应用

双（2-吡啶甲基）胺可用作：
  • 一种反应物，在三乙胺参与下用 ω-碘脂肪族羧酸酯合成双（2-吡啶甲基氨基）链烷酸酯
  • 一种配体，通过用三氯化铁处理来合成双-(2-吡啶甲基)胺的铁络合物，该络合物可用于催化苯直接羟基化为苯酚
  • 一种用于保护羧酸的试剂，如双二甲苯基胺的羧酰胺。

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000308953
0000308953
MKCV2466
MKCR3325
MKCP3723

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Bishnu Das et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 26(65), 14987-14995 (2020-08-28)
In this study we have analysed the comparative photophysical and electrochemical properties of two isomeric heterotrinuclear PtII -IrIII -PtII complexes 3 and 6 and the four corresponding intermediate isomeric homonuclear cyclometalated iridium(III) complexes 1, 2, 4 and 5. The isomerisation
H M Dhammika Bandara et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(14), 3932-3941 (2011-03-03)
Photocages have been used to elucidate the biological functions of various small molecules and Ca(2+) ; however, there are very few photocages available for other metal ions. ZinCleav-2 (1-(4,5-dimethoxy-2-nitrophenyl)-N,N,N',N'-tetrakis-pyridin-2-ylmethyl-ethane-1,2-diamine) is a second-generation photocage for Zn(2+) that releases the metal ion
Yaohui Xu et al.
Materials (Basel, Switzerland), 13(17) (2020-08-23)
Fe3O4@SiO2 nanospheres with a core-shell structure were synthesized and functionalized with bis(2-pyridylmethyl)amine (BPMA). The photoresponses of the as-obtained Fe3O4@SiO2-BPMA for Cr3+, Cd2+, Hg2+ and Pb2+ ions were evaluated through irradiation with a 352 nm ultraviolet lamp, and Fe3O4@SiO2-BPMA exhibited remarkable
M Stylianou et al.
Dalton transactions (Cambridge, England : 2003), 46(11), 3688-3699 (2017-03-04)
A new two-electron photosensitizer, H
Elena R Milaeva et al.
Dalton transactions (Cambridge, England : 2003), 42(19), 6817-6828 (2013-03-16)
A series of Zn, Mn, Fe, Co, and Ni complexes ([MX2L], X = Cl, OAc) of the novel di-(2-picolyl)amine ligand L with an antioxidant 2,6-di-tert-butylphenol pendant were synthesized and characterized by elemental analysis, IR, multinuclear NMR spectroscopy, MALDI-TOF mass spectrometry
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