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Merck
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文件

369500

Sigma-Aldrich

4,4′-亚甲基双(2-甲基环己胺)，异构体混合物

99%

别名:

2,2′-二甲基-4,4′-亚甲基双（环己胺）, 3,3′-二甲基-4,4′-二氨基二环己基甲烷, 4,4′-二氨基-3,3′-二甲基二环己基甲烷, DMDC, 双(3-甲基-4-氨基环己基)甲烷

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About This Item

线性分子式:
CH2[C6H9(CH3)NH2]2
CAS号:
6864-37-5
分子量:
238.41
EC號碼:
229-962-1
MDL號碼:
MFCD00075535
分類程式碼代碼:
12352100
PubChem物質ID:
24862980
NACRES:
NA.22

化驗

99%

形狀

liquid

折射率

n20/D 1.499 (lit.)

bp

93-100 °C (lit.)

密度

0.94 g/mL at 25 °C (lit.)

SMILES 字串

CC1CC(CCC1N)CC2CCC(N)C(C)C2

InChI

1S/C15H30N2/c1-10-7-12(3-5-14(10)16)9-13-4-6-15(17)11(2)8-13/h10-15H,3-9,16-17H2,1-2H3

InChI 密鑰

IGSBHTZEJMPDSZ-UHFFFAOYSA-N

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相关类别

一般說明

4,4′-亚甲基双（2-甲基环己胺）是脂环二胺。

應用

4,4′-可使用亚甲基双（2-甲基环己基胺）(MMCA)：
  • 全脂肪族聚酰亚胺的合成
  • 在全脂肪族聚酰亚胺-硅氧烷 (APISiO) 的合成中
  • 用三羟甲基丙烷三缩水甘油醚制备环氧树脂，用透射 X 射线显微术 (STXM) 表征拖丝的结构组织。

訊號詞

Danger

危險分類

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Corr. 1A

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

343.4 °F - closed cup

閃點（°C）

173 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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S Ohshima et al.
The Journal of toxicological sciences, 11(2), 79-93 (1986-05-01)
Amine-curing agent for epoxy resin, bis(4-amino-3-methyl-cyclohexyl)methane (commercial name; Laromin C) has been suspected to have induced in the workers some toxic signs such as collagen disease like scleroderma or polymyositis. Subacute toxicity of this agent was studied in rats following
Fully aliphatic polyimides from adamantane-based diamines for enhanced thermal stability, solubility, transparency, and low dielectric constant.
Mathews AS, et al.
Journal of Applied Polymer Science, 102(4), 3316-3326 (2006)
Synthesis and characterization of novel fully aliphatic polyimidosiloxanes based on alicyclic or adamantyl diamines.
Mathews AS, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 44(18), 5254-5270 (2006)
Marie-Eve Rousseau et al.
Journal of the American Chemical Society, 129(13), 3897-3905 (2007-03-14)
Nephila clavipes dragline silk microstructure has been investigated by scanning transmission X-ray microscopy (STXM), a technique that allows quantitative mapping of the level of orientation of the peptide groups at high spatial resolution (<50 nm). Maps of the orientation parameter
T Shibata et al.
Virchows Archiv. A, Pathological anatomy and histopathology, 417(3), 203-212 (1990-01-01)
Repeated oral administration of an amine-curing agent for epoxy resin, bis(4-amino-3-methylcyclohexyl)methane, gave rise to severe damage in the choroid plexus of rat brain. The damaged epithelium presented varying degrees of swelling and hydropic vacuolation on light microscopy, and varying numbers
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