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Merck

32950

Sigma-Aldrich

4,4′-二氨基二苯甲烷

≥97.0% (GC)

别名:

4,4′-亚甲基双苯胺, MDA

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About This Item

经验公式(希尔记法):
C13H14N2
CAS号:
分子量:
198.26
Beilstein:
474706
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

≥97.0% (GC)

mp

88-92 °C

溶解度

water: soluble

SMILES 字串

Nc1ccc(Cc2ccc(N)cc2)cc1

InChI

1S/C13H14N2/c14-12-5-1-10(2-6-12)9-11-3-7-13(15)8-4-11/h1-8H,9,14-15H2

InChI 密鑰

YBRVSVVVWCFQMG-UHFFFAOYSA-N

基因資訊

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一般說明

4,4′-二氨基二苯基甲烷作为双齿桥联配体,与其胺的氢原子形成氢键,并且参与多种非共价相互作用。

應用

4,4′-二氨基二苯甲烷已被用于:
  • 作为双酚印迹的虚拟模板
  • 氨基修饰的多壁碳纳米管/聚二甲基硅氧烷的合成
  • 作为固化剂以研究环氧树脂复合材料的形成动力学
  • 在橡胶工业中用作环氧树脂硬化剂

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Carc. 1B - Muta. 2 - Skin Sens. 1 - STOT RE 2 - STOT SE 1

標靶器官

Liver, Liver,eye - retina

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

429.8 °F - closed cup

閃點(°C)

221 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Carcinogenic and chronic effects of 4,4'-diaminodiphenylmethane, an epoxyresin hardener.
R Schoental
Nature, 219(5159), 1162-1163 (1968-09-14)
Cong Hu et al.
Journal of chromatography. A, 1300, 165-172 (2013-06-04)
In this work, amino modified multi-walled carbon nanotubes/polydimethylsiloxane (multi-walled carbon nanotubes-4,4'-diaminodiphenylmethane/polydimethylsiloxane, MWCNTs-DDM/PDMS) was synthesized, and utilized as a novel coating for stir bar sorptive extraction (SBSE) of seven phenols (phenol, 2-chlorophenol, 2-nitrophenol, 4-nitrophenol, 2,4-dimethylphenol, p-choro-m-cresol and 2,4,6-trichlorphenol) in environmental water
Jessica M Labonté et al.
The ISME journal, 9(11), 2386-2399 (2015-04-08)
Viral infections dynamically alter the composition and metabolic potential of marine microbial communities and the evolutionary trajectories of host populations with resulting feedback on biogeochemical cycles. It is quite possible that all microbial populations in the ocean are impacted by
Xiaoli Sun et al.
Journal of chromatography. A, 1343, 33-41 (2014-04-15)
A simple and fast method for both dummy template selection and polymer composition optimization is proposed here. A series of dummy templates for bisphenols imprinting were screened by running them on a non-imprinted polymer (NIP) column with porogen solvent as
A dsc kinetic study on the effect of filler concentration on crosslinking of diglycidylether of bisphenol-A with 4, 4'-diaminodiphenylmethane.
de Miranda MIG, et al.
Polymer, 38(5), 1017-1020 (1997)

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