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Merck

328502

Sigma-Aldrich

二甲基二硒醚

96%

别名:

甲基二硒

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About This Item

线性分子式:
(CH3)2Se2
CAS号:
分子量:
187.99
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

96%

表单

liquid

折射率

n20/D 1.6388 (lit.)

沸点

155-157 °C (lit.)

密度

1.987 g/mL at 25 °C (lit.)

SMILES字符串

C[Se][Se]C

InChI

1S/C2H6Se2/c1-3-4-2/h1-2H3

InChI key

VLXBWPOEOIIREY-UHFFFAOYSA-N

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一般描述

二甲基二硒醚是一种挥发性硒化合物,已报告用 HPLC-电感耦合氩等离子体质谱法测定生物样品中的二甲基二硒醚。用固相微萃取气相色谱-质谱法研究硒与二甲基二硒醚的烷基化反应。

应用

二甲基二硒醚是鉴定阳离子自由基最有效的试剂。

警示用语:

Danger

危险分类

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Flam. Liq. 3 - STOT RE 2

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

140.0 °F - closed cup

闪点(°C)

60 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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William J Hunter et al.
Journal of chromatography. A, 1038(1-2), 295-297 (2004-07-06)
A simple method for the determination of volatile selenium compounds employing a gas chromatograph equipped with a photoionization detector is described. The method involves the direct injection of dimethylselenide (DMS) or dimethyldiselenide (DMDS) into the gas chromatograph; no derivatization of
Kathrin Schilling et al.
Journal of environmental quality, 40(3), 1021-1027 (2011-05-07)
If volatile organoselenides are to be analyzed for their stable Se isotope composition to elucidate sources and formation processes, organoselenides need to be trapped quantitatively to avoid artificial Se isotope fractionation. We developed an efficient trap of organoselenides to be
Elimination of selenium compounds by mice through formation of different volatile selenides.
S Jiang et al.
Experientia, 39(3), 293-294 (1983-03-15)
Yiqiang Zhang et al.
Journal of environmental quality, 31(4), 1124-1128 (2002-08-15)
Volatilization of dimethyldiselenide (DMDSe) is one of the most important processes for removing selenium (Se) from Se-contaminated environments. However, the fate of DMDSe in soil is not known. In this study, we monitored the changes of DMDSe in the head
J E Spallholz et al.
Nutrition and cancer, 40(1), 34-41 (2002-01-22)
The reduction of cancer incidence by dietary supplementation with L-selenomethionine, L-Se-methylselenocysteine, and other methylated selenium compounds and metabolites is believed to be due to the metabolic generation of the monomethylated selenium species methylselenol. Dimethyldiselenide and methylseleninic acid were reduced by

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