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Merck

316954

Sigma-Aldrich

过铼酸铵

≥99%

别名:

偏麦角酸铵盐, 铼标准品溶液

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About This Item

线性分子式:
NH4ReO4
CAS号:
分子量:
268.24
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23

等级

for analytical purposes

方案

≥99%

表单

powder or crystals

反应适用性

reagent type: catalyst
core: rhenium

密度

3.97 g/mL at 25 °C (lit.)

SMILES字符串

N.O[Re](=O)(=O)=O

InChI

1S/H3N.H2O.3O.Re/h1H3;1H2;;;;/q;;;;;+1/p-1

InChI key

XPSXHXWHJAIQJR-UHFFFAOYSA-M

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一般描述

高铼酸铵是一种白色结晶固体,溶于乙醇和水。它是一种弱氧化剂,广泛用作纳米材料合成和Re基催化剂制备的Re前驱体。

应用

高铼酸铵可用于:
  • 作为铼源制备Re纳米颗粒,用于催化分解高氯酸铵。
  • 直接硫化反应法合成ReS2, 用于制造场效应晶体管(FET)、数字逻辑器件、湿度传感器和可充电超级电容器。
  • 作为制备有机转化用多相催化剂的前驱体。
  • 制备用于脱氧脱水的ReOx/TiO2可回收固体催化剂的优良前驱体。。在至少连续六次反应中,该催化剂均表现出催化活性、选择性和稳定性,且不会失活。

储存分类代码

13 - Non Combustible Solids

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Perez-Lourido, P. et al.
Inorganic Chemistry, 38, 1511-1511 (1999)
Xuezeng Tian et al.
Nature materials, 19(8), 867-873 (2020-03-11)
The electronic, optical and chemical properties of two-dimensional transition metal dichalcogenides strongly depend on their three-dimensional atomic structure and crystal defects. Using Re-doped MoS2 as a model system, here we present scanning atomic electron tomography as a method to determine
Zixuan Wang et al.
Small (Weinheim an der Bergstrasse, Germany), 16(20), e2000852-e2000852 (2020-04-24)
Tuning bandgap and phases in the ternary 2D transition metal dichalcogenides (TMDs) alloys has opened up unexpected opportunities to engineer optoelectronic properties and explore potential applications. In this work, a salt-assisted chemical deposition vapor (CVD) growth strategy is reported for
Jeffrey G Linger et al.
Proceedings of the National Academy of Sciences of the United States of America, 111(33), 12013-12018 (2014-08-06)
Lignin is an energy-dense, heterogeneous polymer comprised of phenylpropanoid monomers used by plants for structure, water transport, and defense, and it is the second most abundant biopolymer on Earth after cellulose. In production of fuels and chemicals from biomass, lignin
Yuee Feng et al.
Inorganic chemistry, 48(23), 11058-11066 (2009-11-06)
The detailed syntheses of complexes of the form [Re(O)(X)(RNCH(2)CH(2))(2)N(Me)] (X = Me, Cl, I, R = mesityl, C(6)F(5)), 1-3, incorporating diamidoamine ancillary ligands are described. X-ray crystal structures for the complexes [Re(O)(Me)((C(6)F(5))NCH(2)CH(2))(2)N(Me)], 1a, [Re(O)(I)((C(6)F(5))N CH(2)CH(2))(2)N(Me)], 3a, and [Re(O)(I)((Mes)NCH(2))(2)N(Me)], 3b, are

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